Page 162 - Handbook of Adhesion Promoters
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8.13 Polyetheretherketone                                            155


            8.13 POLYETHERETHERKETONE

            Dow Corning Z-6106 is suggested for adhesion promotion of polyetheretherketone.
                Zinc  oxide  coatings  were  deposited  by  magnetron  sputtering  on  the  surface  of
                 1
            PEEK.  These thin films exhibit the zincite form with a preferred orientation along the
                    1
            [002] axis.  Their microstructure varies from a large columnar structure to a more regular
                                              1
            one depending on the process parameters.  The adhesion is promoted by argon plasma
                    1
                                                               1
            treatment.  The plasma treatment changes the polar component.  The adhesion strength of
            zinc oxide films is linked to the kinetic energy of the sputtered particles; the atomic bom-
            bardment of the polymer surface during the deposition of the ZnO coating is the dominant
                 1
            factor.
                The conductive coated PEEK filament yarn can be used as a textile-based electro-
                                                            2
            conductive functional element, especially in a strain sensor.  Silver is applied on the sur-
                                2
            face using wet procedure.  To improve adhesion of the Ag layer, the PEEK monofilament
            surface is treated with an atmospheric pressure plasma and it is subsequently coated with a
                                         2
            polyamine-based adhesion promoter.
                The adhesion between the polyetheretherketone matrix and titanium fiber degrades
                                   3
            by the influence of humidity.  The laser pre-treatment offers the best humidity resistance
                                             3
            because of its effect on surface roughness.  The adhesion promoter causes enhanced initial
                                                       3
            bonding strength but also reduced humidity resistance.
            REFERENCES
            1  Giancaterina, S; Amor, SB; Bachari, EM; Baud, G; Jacqueta, UM; Perrin, C, Surf. Coat. Technol.,
               138, 84-94, 2001.
            2  Hasan, MMB; Foisal, ABM; Onggar,T; Hund, RD; Nocke, A, Compos. Sci. Technol., 88, 76-83, 2013.
            3  Schultze, K; Hausmann, J; Wielage, B, Procedia Mater. Sci., 2, 92-102, 2013.
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