Page 97 - Handbook of Surface Improvement and Modification
P. 97

92                                                              Tackifiers


                          28
            ing temperatures.  Lower viscosity also helps the adhesive to “wet out,” or to uniformly
                                               28
            coat the surface and penetrate the substrate.  Any conventionally known tackifier, which
                                                                 28
            is suitable for use in formulating hot-melt adhesives, may be used.   A preferred tackifier
            comprises  a  modified  rosin  (such as an ester modified rosin), an  aromatic  modified
                                                    28
            cycloaliphatic  hydrocarbon  resin,  or  polyterpene.   The  hot-melt  adhesive  composition
            has properties at elevated temperatures or at low refrigerator and freezer temperatures that
                                                              28
            other conventional adhesives have been unsuccessful to reach.
                A  percutaneous  absorption  preparation  for  treatment  of  dementia  that  comprises
            rivastigmine or its pharmaceutically acceptable salt as an active ingredient, a styrene-iso-
            prene-styrene block copolymer, a tackifier resin ( selected from the group consisting of an
            alicyclic hydrocarbon resin, an aliphatic hydrocarbon resin, a hydrogenated hydrocarbon
            resin, a rosin-based resin, a terpene-based resin, and a polyester resin), and a plasticizer
            (selected from a group consisting of petroleum oil, squalane, plant oil, synthetic oil, diba-
            sic acid ester, liquid rubber, liquid fatty acid ester, diethylene glycol, polyethylene glycol,
            glycol salicylate, propylene glycol, dipropylene glycol, triacetin, triethyl citrate, and cro-
                   29
            tamiton).   Preferably, the tackifer may be either alicyclic hydrocarbon resins or aliphatic
            hydrocarbon resins, or their mixtures (e.g.  alicyclic hydrocarbon resins such as a styrene-
                                                29
            α-methyl styrene resin (e.g., Kristalex F85)).  The preparation allows a sufficient amount
            of  the  active  ingredient  to  penetrate  into  the  skin  to  achieve  an  effective  treatment  of
                    29
            dementia.
                Valve-through tire puncture sealant compositions includes anti-freezing agents and
                       30
            rigid particles.  The aqueous solution with 0.1-10 wt% dissolved biomaterials and 0.1-10
            wt% tackifier (sodium alginate) is mixed with anti-freezing agent, in which 0.01-5 wt%
            rigid particles of biomaterials (chitosan) and other particles (kaolinite, silica, and colloidal
                             30
            silica) are suspended.  Tackifier is added to increase the viscosity of the solution and to
                                                                               30
            improve the tack of the rigid and flexible suspended solids to the punctured wall.  The
            sealant composition is environmentally friendly, has insignificant settling, and long shelf-
               30
            life.  The sealant is capable of sealing puncture formed by less than or equal to 6.35 mm
                                                   30
            spike for long duration, i.e., more than 30 hours.
                Tackified pressure-sensitive adhesives and tapes comprise a copolymer based on an
            acrylic backbone, with a glycidyl monomer, unsaturated carboxylic acid monomer, and a
                   31
            tackifier.  The adhesive has dual cure (heat and aziridine) and has a combination of out-
            standing peel adhesion on the low surface energy substrates, high temperature shear per-
                                                                               31
            formance, excellent stress relieving properties, and excellent converting properties.  The
            selection of tackifying resin and its amount should be considered in formulation as well as
                                                                      ®
                                               31
            the type of acrylic polymer being tackified.  Some resins, such as Foral  85, are broadly
                                           31
            compatible with acrylic compositions.  Others, like Regalrez™ 6108, tackify a limited
                                31
            number of compositions.  The type of tackifying resin and the amount employed is to be
            compatible with the acrylic polymer which means that when the tackifier and copolymer
                                                              31
            are combined, the resulting combination should be transparent.
                The polyamide films are widely used in packaging applications, due to their superior
                            32
            puncture resistance.  They are used to make puncture-resistant bags for meat and other
            food types, but the processes for making the bags typically involve high temperatures to
                       32
            seal the bags.  A potential way of addressing the problem is to provide a heat seal layer
            on polyamide via solution coating rather than using blown film or extrusion processes. 32
   92   93   94   95   96   97   98   99   100   101   102