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Industrial Wastewater Treatment, Recycling, and Reuse: An Overview  45





                                                               Biogas/
                                                  Anaerobic    energy
                                                 wastewater
                                                  treatment



                                                  Aerobic
                Untreated      Primary           wastewater           Treated
                wastewater     treatment         treatment           wastewater
                                       Solids
                                                       Solids
                                    Anaerobic
                                    wastewater
                                    treatment
                                                 Biogas/
                                                 energy

                                    Sludge for
                                     disposal
              Figure 1.17 Combined aerobic/anaerobic process for wastewater treatment.

              to develop better separation technologies in physico-chemical treatments with
              an emphasis on adsorption, ion exchange, oxidation, cavitation, and mem-
              brane separation along with the development of hybrid systems. It should
              be noted that in the area of adsorption, the focus had been largely on process
              development and not on materials, while in the membranes area, the focus had
              been mostly on the material science while the process application area lacked
              attention. As mentioned earlier, the energy costs in advanced effluent treat-
              ment methods are tremendous, and thus emphasis is required today on
              new adsorbent and ion exchange materials with increased capacity, selectivity,
              and kinetics to improve separations at substantially reduced cost. Effective
              regeneration of materials is also critical to efficient operation and increased life.
              Demonstration of performance in real-world systems is crucial since most of
              the work reported deals predominantly with clean/ideal systems. This is espe-
              cially true for membrane separations since membrane fouling problems, tem-
              perature stability, chemical/mechanical stability, and separation characteristics
              are tested in real-world systems, where most failures occur. All these tech-
              niques of adsorption/ion exchange/membrane separation along with newer
              processes such as cavitation are most suitable for development of hybrid sys-
              tems where reaction-separation occurs (i) in one step or (ii) in combination
              with two or more separation techniques.
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