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Industrial Wastewater Treatment, Recycling, and Reuse: An Overview  55


              Thailand. DyStar, Ciba, Specialty Chemicals, and Clariant are some of the
              world’s leading manufacturers of dyes. Regulatory barriers have nearly
              stopped progress in opening fundamentally new dyestuff manufacturing
              facilities. The manufacturers are, however, continuing to add to their pro-
              duction of reactive and specialty dyes. Among the developing nations,
              China’s production of dyes and organic pigments is increasing at a fast rate.
              In 2004, the production share of the United States and Europe was reported
              to be 24% and 22% respectively.


              1.5.2.3 Dye Wastewater Treatment: Overview and Recommendations
              Typically, the dye industry handles different types of dyes, most prominent of
              which are acid and direct dyes, disperse dyes, sulfur dyes, reactive dyes, and vat
              dyes, while the dye intermediate industry produces H-acid, vinyl sulfone, and
              gamma acid as the main products. A conventional water pattern in small- to
              medium-scale dyestuff manufacturers is shown in Figure 1.18.


                         Reactive dyes                Acid and direct dyes
                                                                    Raw
                                     Raw
                                                                   material
                                    material                       T/T, 1.97
                                    T/T, 1.5
                                                   Liquid
                    Liquid       Process          effluent       Process
                    effluent      water            T/T, 14        water
                    T/T, 30.9    T/T, 33.8                        T/T, 16






                           Pigment                        Dyes general

                                      Raw                               Raw
                                     material                          material
                                     T/T, 5.7                          T/T, 12.2
                     Liquid                         Liquid
                    effluent                       effluent
                    T/T, 23.6  Process             T/T, 26.5  Process
                                water                          water
                               T/T, 44.2                       T/T, 32




              Figure 1.18 Typical water and wastewater scenario in small scale dyes industry.
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