Page 262 - Instrumentation Reference Book 3E
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246  Temperature measurement
            to the emergent column of mercury and the glass   Glass  thermometers  used  in  industry  are
            stem being at a different temperature than the bulb.   usually protected by metal sheaths. These sheaths
            Errors introduced this way should be allowed for if   may conduct heat to or from the neighborhood of
            accurate  readings  are  required.  Some  therm-   the thermometer bulb and cause the thermometer
            ometers, however, are calibrated for partial immer-   to read either high or low according to the actual
            sion and should be used immersed to the specified   conditions  prevailing.  A  thermometer  should,
            depth.                                   therefore, be calibrated, whenever possible, under
              When  reading  a  thermometer  an  observer   the conditions in which it will be used, if accurate
            should keep his eye on the same level as the top   temperature  readings  are  required.  If,  however,
            of the mercury column. In this way errors due to   the  main  requirement  is  that  the  temperature
            parallax will be avoided.                indication  be  consistent for the same plant tem-
              Figure  14.3 shows the  effect of  observing the   perature,  then  an  error  introduced  is  not  so
            thermometer  reading  from  the  wrong  position.   important,  so long as the conditions  remain the
            When  viewed  from  (a)  the  reading  is  too  high.   same, and the error is constant.
            Taken from (b) the reading  is correct, but  from
            (c) it is too low.
              A  mercury-in-glass thermometer  has  a  fairly   Errors due to aging  It is often assumed that pro-
            large  thermal  capacity  (i.e.,  it  requires quite  an   vided a mercury-in-glass thermometer  is in good
            appreciable amount of heat to change its tempera-   condition it will always give an accurate reading.
            ture by one degree), and glass is not a very good   This  is  not  always  so,  particularly  with  cheap
            conductor of heat. This type of thermometer will,   thermometers.  A  large error may be introduced
            therefore,  have  a  definite thermal  lag.  In  other   by changes in the  size of  the bulb  due to aging.
            words, it will require a definite time to reach the   When glass is heated to a high temperature,  as it
            temperature of its surroundings. This time should   is when  a thermometer  is made, it does not, on
            be allowed for before any reading is taken. If there   cooling, contract to its original volume immedi-
            is  any doubt  as to whether the thermometer has   ately. Thus, for a long time after it has been made
            reached equilibrium with a bath of liquid having a   the bulb continues to contract very slowly so that
            constant  temperature,  then  readings  should  be   the original zero mark is too low on the stem. and
            taken at short intervals of time. When the reading   the thermometer reads high. This error continues
            remains constant the thermometer must be in equi-   to increase over a long period, and depends upon
            librium with the bath. If the temperature is varying   the type of glass used in the manufacture of the
            rapidly  the  thermometer may  never indicate the   thermometer.  In order to reduce to a minimum
            temperature  accurately, particularly if  the  tested   the  error  due to this cause, during  manufacture
            medium is a gas.                         thermometers are annealed by baking for several
                                                     days at a temperature above that which they will
                                                     be  required to measure, and then  cooled slowly
                                                      over a period of several days.
                                                       Another  error  due  to  the  same  cause  is  the
                                     - Capillary     depression  of  the  zero  when  a  thermometer  is
                                       tube          cooled  rapidly  from  a  high  temperature.  When
                                                     cooled, the  glass of  the  thermometer  bulb  does
                                                      not contract immediately to its original size so that
                                                      the reading on the theimometer at low temperature
                                                      is too low, but returns to normal after a period of
                                                      time. This period depends upon the nature of  the
                                                      glass from which the bulb is made.


                                                      High  teinperature  tlzerniometers  Mercury  nor-
                                  I  Mercury          mally boils at 357 "C at atmospheric pressure. In
                                                      order to extend the range  of  a mercury-in-glass
                                                      thermometer  beyond  this  temperature,  the  top
                                                      end  of  the  thermometer  bore  is  enlarged into a
                                                      bulb having a capacity of about 20 times that of
                                                      the bore of the stem. This bulb, together with the
                                                      bore above the mercury, is then filled with nitro-
                                                      gen or carbon dioxide at a sufficiently high pres-
                                                      sure to prevent the mercury boiling at the highest
            Figure 14.3  Parallaxerrorswhen reading glass
            thermometerer.                            temperature  at  which  the  thermometer  will  be
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