Page 247 - Introduction to Computational Fluid Dynamics
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                                                                                     PHASE CHANGE
                                          h l                                      May 25, 2005  11:14


                            h           λ                             Figure 7.7. h ∼ T relation for an impure
                                                                      material.
                                  h s


                                   SOLID       MUSH           LIQUID
                                           T s          T m


                            are employed:

                                                    h − h s
                                                 =        ,    h s = C ps T s ,                (7.34)
                                                      λ
                                                    C ps (T − T s )
                                                θ =             ,                              (7.35)
                                                         λ
                                                    α s t
                                                τ =    ,                                       (7.36)
                                                     L 2
                                                    x
                                               X =    ,                                        (7.37)
                                                    L
                                                    ρ            K            C p
                                                ∗           ∗            ∗
                                               ρ =    ,    k =     ,    C =      .             (7.38)
                                                                         p
                                                    ρ s         K s          C ps
                            Therefore, Equation 7.4 can be written as


                                                        ∗
                                                     ∂(ρ  )     ∂      ∂θ
                                                             =      k  ∗                       (7.39)
                                                       ∂τ      ∂ X     ∂ X
                            and the equations of state will take the form

                                             θ =       for      ≤ 0,                           (7.40)

                                             θ = f ( )    for    0 < < 1,                      (7.41)
                                                       C ps
                                             θ = θ m +    (  − 1)     for     > 1.             (7.42)
                                                       C pl
                               For alloys, function f ( ) may take a variety of forms. For Al–4.5% Cu alloy, for
                            example,VollerandSwaminathan[85]haveusedthefollowinggeneralrelationship:

                                                            n
                                                    θ − θ s
                                                =                for    θ s <θ <θ l            (7.43)
                                                    θ l − θ s
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