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                        7.3 1D PROBLEMS FOR IMPURE SUBSTANCES
                                         St = 3.0                                  May 25, 2005  11:14 225
                           0.8                   St = 1.0


                                                                         St = 0.25
                           0.6

                          Xi(t)

                           0.4




                           0.2


                                                                         DAYS
                           0.0
                                          5            10           15            20
                        Figure 7.6. Solutions for X i (t).

                        are predicted that agree with the exact solution well. In each case, solutions are
                                            2
                        obtained with  τ/ X = 2, which is 10 times larger than that used in Figure 7.3.
                        Thus, inclusion of θ pc, j permits the use of coarse grids and allows large time steps
                        and yet yields accurate solutions. This finding is particularly important for multi-
                        dimensional problems. Figure 7.6 shows the variation of X i (as calculated using
                        Equation 7.23) with time. It is seen that as the Stefan number increases, the interface
                        moves faster. Notice that for St = 1 and St = 3, the computations are carried on
                        even after the complete domain is solidified; hence, the interface location appears
                        to remain stationary at 1 m.


                        7.3 1D Problems for Impure Substances

                        In impure materials or alloys, phase change takes place over a range of temperatures
                        T s < T < T l where T s and T l may be termed as solidus and liquidus temperature,
                        respectively. Here, we shall permit different properties of solid and liquid phases.
                        The h ∼ T relation, therefore, may appear as shown in Figure 7.7. In this figure,
                        the region (also called the mushy region) between T s and the fusion temperature T m
                        is shown blank because the h ∼ T relation may take a variety of forms in different
                        materials.
                           The energy equation (7.4) will again be applicable. To account for different
                        properties of the two phases, however, the following dimensionless variables
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