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4.3. Fast Electro-optic Switches: Modulators  253

       bandgap material. Because of thin wells, the behavior of electrons and holes in
       these two-dimensional (2D) potentials alters their density-of-states functions in
       such a way that the absorption edge is sharpened. In addition, the motion of
       electrons and holes is constrained by their confinement, leading to discrete
       energy levels in the wells. Because of the 2D nature of the electron -hole gas in
       quantum wells, exciton binding energy is increased with respect to the bulk
       semiconductor so as to make excitons observable at room temperature in the
       absorption spectrum of MQW.
          The principle of MQW modulators can be illustrated using Fig. 4.25. If an
       electric field is applied perpendicularly to the quantum-well layers, the energy
       levels in the wells change and modify the zero-point energies of the particles.
       This effect, called QCSE, arises because of the difference in the potential wells
       seen by the particles. The electron and hole wave functions are modified to
       reduce the zero-point energies so as to decrease the effective bandgap of the
       quantum wells. As a consequence, the increase in the electric field applied to
       the wells reduces the energy required to generate electron hole pairs, so that
       the exciton absorption peaks move toward lower energy. The optical trans-
       mission spectra for varying applied voltage for a GaAs/AlGaAs single quantum
       well is shown in Fig. 4.26.
          One of the most effective ways to apply the necessary voltage to the
       quantum wells is to make a diode with quantum wells in the middle. As the
       diode is reverse biased, the electric field is applied perpendicular to the
       quantum-well layers. In a reverse-biased diode, the necessary field can be
       applied without having any current flowing, which makes this a particularly
       efficient device. The device shown in Fig. 4.26 is made using GaAs and AlGaAs
       semiconductor materials. The modulator works best typically at wavelengths



                             10 4

                                            V = OV
                                      6V
                          ti
                          I
                          I

                              1.43        Eo       1.48

                                    Photon Energy E (eV)
       Fig. 4.26. QCSE shift of absorption spectrum for a GaAs quantum well sample with different
       external fields [31]. Photon energy E is related to optical wavelength through },(nm) = 1.242/E
       (eV).
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