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Principles and operation of refrigeration and heat pump systems    21

                     5.0

                     4.5
                     4.0
                    Ideal coefficient of performance  3.0  T ,  C
                     3.5


                     2.5
                             o
                           L
                     2.0
                             -5
                            -10
                     1.5
                     1.0
                            -50
                     0.5    -25
                     0.0
                        50     100     150    200     250     300    350
                                                         o
                                     Heat source temperature,  C

           Fig. 1.15 Ideal COP for absorption refrigerators: T A ¼ 25 C.

           heat. This type of system was commercialized in 1933 when many homes were con-
           nected to municipal natural gas service. Figure 1.16 shows a simplified schematic of
           such a machine. There are three working fluids: ammonia (the coolant), water (the
           absorber) and hydrogen (a catalyst).
              The heat input at the generator (3) is supplied by a gas burner. At that place, the
           working fluid is a liquid mixture of ammonia and water. The ammonia having the
           lower boiling point boils off and percolates up a tube, lifting the water-ammonia
           mixture to the rectifier (4) where the hot vapor (nearly pure ammonia) is separated
           and rises to the condenser (5). There it comes in thermal contact with the ambient tem-
           perature room air, releases its latent heat and liquefies. It then passes through a trap
           (throttle) and into coils surrounding the freezer section of the refrigerator (1). The
           now cold ammonia receives heat from the freezer space and evaporates. However,
           before the ammonia enters the freezer it mixes with hydrogen gas rising from the
           absorber (2), creating a denser fluid than either of the fluids alone. This allows the
           ammonia and hydrogen mixture to fall under its own weight to the absorber (2) where
           the ammonia is absorbed into the water that had been separated at the rectifier.
           Hydrogen cannot absorb into the water (water is saturated with hydrogen) and is
           released to rise through the absorber coils where it passes through the descending water
           and eventually rises to the freezer, completing a loop of travel. The hydrogen releases
           heat at the coils, giving up the heat it had picked up in the freezer.
              No mechanical work or electricity is needed to operate this RM, only heat from
           burning natural or bottled gas, making these units popular for remote residences
           such as hunting cabins. Of course, if one desires a light bulb inside the refrigerator
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