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Chapter 4  Metal Alloys: Their Structure and Strengthening by Heat Treatment

                                    " 500                                A  300
                                    Li’
                                    3                                    ii’
                                    .Q 400                               5 200


                                    `=7= 300                             ‘<7> 100
                                    2                                    E
                                    'G                                   .Q
                                    C                                    >-
                                    ii’ 200                                   0
                                         0   25   50   75  100 Ni0rZn          0   25   50   75  100 NiorZn
                                        100  75   50   25   0  Cu             100  75   50   25   0  Cu
                                             Composition (%)                      Composition (%)

                                      120                                A   70
                                                                          g
                                    A                                     E           Zinc
                                    Ei 100                               3   60
                                                                          C
                                    -f                                   --  50
                                    §  80                                5,
                                    _E                                   5   40
                                       6°                                 §» so
                                    iz”
                                                                          O
                                       40                                E   20
                                         0    25  50   75  100 NiorZn          0   25   50   75  100 NiorZn
                                        100   75  50   25   0  Cu             100  75   50   25   0  Cu
                                             Composition (%)                      Composition (%)


                                   FIGURE 4.6  Mechanical properties of copper-nickel and copper-zinc alloys as a function of
                                   their composition. The curves for zinc are short, because zinc has a maximum solid solubility
                                   of 40% in copper.


                                               350 32706
                                               300 _                    Liquid

                                            Sl 250 `    of + iiquid       Liquid + B  232%
                                            g 200 _  a         183OC     61.9%
                                            E     _      19.2%
                                            él 150             Ol + B  Eutectic      B
                                            .9 100 -

                                                50
                                                 O
                                                  0      20      40     60      80     100 Tin (Sn)
                                                 100     80      60     40      20      0  Lead (Pb)
                                                           Composition (% by weight)

                                   FIGURE 4.1  The lead-tin phase diagram. Note that the composition of the eutectic point for
                                   this alloy is 61.9% Sn-38.1% Pb. A composition either lower or higher than this ratio will
                                   have a higher liquidus temperature.

                                   liquid, namely, 183°C. This point is known as the eutectic point, and it is the point
                                   at which the liquid solution decomposes into the components alpha and beta. The
                                   Word eutectic is from the Greek eute/etos, meaning “easily melted.”
                                        Eutectic points are important in applications such as soldering (Section 323),
                                   where low temperatures are desirable to prevent thermal damage to parts during
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