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|22 1000  Chapter 4  Metal Alloys: Their Structure and Strengthening by Heat Treatment

          .3 8O0_
                                                                   The annealing process may be carried out in an
                                                              formed at lower temperatures to minimize or prevent
          A 900  _. 2   \                                     inert or a controlled atmosphere, or it may be per-
                           Normalizing
          O                                    Acm            surface oxidation.
                                                                   An annealing temperature may be higher than
          12/                             Full                the material’s recrystallization temperature, depend-
                                          annealing
                   A3
                                                              ing on the degree of cold work. For example, the
                                                              recrystallization temperature for copper ranges be-
          I9 700-    A                                        tween 200° and 300°C, whereas the annealing tem-
                                                              perature needed to  fully  recover the  original
                                      Spheroidizing
                                                              properties ranges from 260° to 65 0°C, depending on
                      1
                                                              the degree of prior cold work (see also Section 1.6).
             6000   0.2  0.4  0.6  0.8  1.0  1.2  1_4  1.6
                                                              Full annealing is a term applied to the annealing of
                           Composition (% C)
                                                              ferrous alloys. The steel is heated to above A1 or A3
                                                              (Fig. 4.23), and the cooling takes place slowly [typi-
          FIGURE 4.23  Heat-treating temperature ranges for plain-
          carbon steels, as indicated on the iron-iron carbide phase  cally at 10°C per hour], in a furnace, after which it is
                                                              turned off. The structure obtained through full an-
          diagram.
                                                              nealing is coarse pearlite, which is soft and ductile
                                                              and has small, uniform grains.
             800
                                                    70             To avoid excessive softness from the annealing
             700-                     _  Quenehed             of steels, the cooling cycle may be done completely in
          ED. eoo -                   it            60        still air. This process is called normalizing, to indicate
                                                              that the part is heated to a temperature above A3 or
          EE soo -        »
                                                              Acm in order to transform the structure to austenite.
           § 400-                                   so  FQ
                                                              Normalizing results in somewhat higher strength and
          Q soo-               mm,@g».1,@¢                    hardness, and in lower ductility, than does full an-
          I 200-                                    40        nealing (Fig. 4.24). The structure obtained is fine
                                                              pearlite, with small, uniform grains. Normalizing is
             ioo -
                                                              generally carried out to refine the grain structure,
               0
                0  0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0    obtain uniform structure (homogenization), decrease
                                                              residual stresses, and improve machinability. The
                          Carbon content (%)
                                                              structure of spheroidites and the procedure  for
          FIGURE 4.24  Hardness  of steels  in the quenched and  obtaining it were described in Section 4.7 and shown
          normalized conditions as a function of carbon content.  in Figs. 4.14 and 4.23. Splaeroidizing annealing
                                                              improves the cold workability (Section 4.7) and the
                                    machinability of steels (Section 21.7).

                                    Process Annealing.  During process annealing (also called intermediate annealing,
                                    subcritical annealing, or in-process annealing), the workpiece is annealed to restore
                                    its ductility, part or all of which may have been exhausted by cold working.
                                    Afterwards, the part can be worked further into the final desired shape. If the tem-
                                    perature is high and/or the time of annealing is long, grain growth may result
                                    (Section 1.6), with adverse effects on the formability of the annealed parts.

                                    Stress-relief Annealing.  To reduce or eliminate residual stresses, a workpiece is
                                    generally subjected to stress-relief annealing, or simply stress relieving. The temper-
                                    ature and time required for this process depend on the material and on the magni-
                                    tude of the residual stresses present. The residual stresses may have been induced
                                    during forming, machining, or other shaping processes, or they may have been
                                    caused by volume changes during phase transformations.
                                        For steels, the part is not heated to as high as A1 in Fig. 4.23, in order to avoid
                                    phase transformations; slow cooling, such as occurs in still air, is generally em-
                                    ployed. Stress relieving promotes dimensional stability in situations where subse-
                                    quent relaxing of residual stresses may cause distortion of the part when it is in
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