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Section 5 3  Casting of lngots



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                   Charging scrap into furnace  Charging molten iron  Addition of burnt lime
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                  Blowing with oxygen       Tapping the furnace     Pouring the slag
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              FIGURE 5.3  Schematic illustrations showing charging, melting, and pouring of molten iron
              in a basic-oxygen process.


              5.3    Casting of lngots

              Traditionally, the next step in the steelmaking process is the shaping of the molten
              steel into a solid form (ingot) for such further processing as rolling it into shapes,
              casting it into semifinished forms, or forging it. The molten metal is poured (teemed)
              from the ladle into ingot molds, in which the metal solidifies. Molds usually are
              made of cupola iron or blast-furnace iron with 3.5% carbon. They are tapered in
              order to facilitate the removal of the solidified metal. The bottoms of the molds may
              be closed or open; if they are open, the molds are placed on a flat surface. The
              cooled ingots are removed (stripped) from the molds and lowered into soaking pits,
              where they are reheated to a uniform temperature of about 1200°C for subsequent
              processing by rolling. lngots may be square, rectangular, or round in cross section,
              and their weights range from a few hundred kilograms to 36 metric tons.
                   Certain reactions take place during the solidification of an ingot that have an
              important influence on the quality of the steel produced. For example, significant
              amounts of oxygen and other gases can dissolve in the molten metal during steel-
              making. Most of these gases are rejected during the solidification of the metal, be-
              cause the solubility limit of the gases in the metal decreases sharply as its temperature
              decreases (see Fig. 10.15 ). Rejected oxygen combines with carbon to form carbon
              monoxide, which causes porosity in the solidified ingot.
                   Depending on the amount of gas evolved during solidification, three types of
              steel ingots can be produced: killed, semi-killed, and rimmed.
                 I. Killed Steel. Killed steel is a fully deoxidized steel; that is, oxygen is removed
                   and the associated porosity is thus eliminated. In the deoxidation process, the
                   dissolved oxygen in the molten metal is made to react with elements such as
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