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Chapter 5  Ferrous Metals and Alloys: Production, General Properties, and Applications

                                        Titanium improves hardenability; it deoxidizes steels.
                                        Tungsten has the same effects as cobalt.
                                        Vanadium improves strength, toughness, abrasion resistance, and hardness at
                                           elevated temperatures; it inhibits grain growth during heat treatment.
                                        Zirconium has the same effects as cerium.



                                   5.5.2 Residual Elements in Steels
                                   During steel production, refining, and processing, some residual elements (trace ele-
                                   ments) may remain. Although the elements in the preceding list also can be considered
                                   as residuals the followin g g enerall are considered unwanted residual elements:
                                             >                  Y
                                        Antimony and arsenic cause temper embrittlement.
                                        Hydrogen severely embrittles steels; however, heating during processing drives
                                           out most of the hydrogen.
                                        Nitrogen improves strength, hardness, and machinability; in aluminum-
                                           deoxidized steels, it controls the size of inclusions. Nitrogen can increase or
                                           decrease strength, ductility, and toughness, depending on the presence of
                                           other elements.
                                        Oxygen slightly increases the strength of rimmed steels; it severely reduces
                                           toughness.
                                        Tin causes hot shortness and temper embrittlement.




                                   5.5.3 Designations for Steels
                                   Traditionally, the American Iron and Steel Institute (AISI) and the Society of
                                   Automotive Engineers (SAE) have designated carbon and alloy steels by using four
                                   digits. The first two digits indicate the alloying elements and their percentages, and
                                   the last two digits indicate the carbon content by weight.
                                        The American Society for Testing and Materials (ASTM) has another designa-
                                   tion system, which incorporates the AISI and SAE designations and includes stan-
                                   dard specifications for steel products. For ferrous metals, the designation consists of
                                   the letter “A” followed by a few numbers (generally three). The present numbering
                                   system is known as the Unified Numbering System (UNS) and has been adopted
                                   widely by ferrous and nonferrous industries. It consists of a letter indicating the gen-
                                   eral class of the alloy, followed by five digits designating its chemical composition.
                                   Typical letter designations are as follows:
                                        G-AISI and SAE carbon and alloy steels
                                        ]-cast steels
                                        K-miscellaneous steels and ferrous alloys
                                        S-stainless steels and superalloys
                                        T-tool steels
                                   Two examples are G413OO for AISI 4130 alloy steel and T30108 for AISI A-8 tool
                                   steel.


                                   5.5.4 Carbon Steels
                                   Carbon steels generally are classified by their proportion (by weight) of carbon con-
                                   tent. The general mechanical properties of carbon and alloy steels are shown in
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