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238       Chapter 10  Fundamentals of Metal Casting
                                   it affects the rate of cooling. The chapter finishes with a description of the factors
                                   influencing defect formation.
                                        Industrial metal-casting processes, design considerations, and casting materials
                                   are described in Chapters 11 and 12. The casting of ceramics and of plastics, which
                                   involves methods and procedures somewhat similar to those for metal, are described
                                   in Chapters 18 and 19, respectively.



                                    |0.2    Solidification of Metals


                                   After molten metal is poured into a mold, a series of events takes place during the
                                    solidification of the metal and its cooling to ambient temperature. These events
                                   greatly influence the size, shape, uniformity, and chemical composition of the grains
                                    formed throughout the casting, which in turn influence the overall properties of the
                                    metal. The significant factors affecting these events are the type of metal, the ther-
                                    mal properties of both the metal and the mold, the geometric relationship between
                                    volume and surface area of the casting, and the shape of the mold.

                                    l0.2.l Pure Metals

                                    Because a pure metal has a clearly defined melting (or freezing) point, it solidifies at
                                    a constant temperature, as shown in Fig. 10.1. Pure aluminum, for example, solidi-
                                    fies at 660°C, iron at 1537°C, and tungsten at 3410°C. (See also Table 3.1 and Fig.
                                    4.4.) After the temperature of the molten metal drops to its freezing point, its tem-
                                    perature remains constant while the latent heat of fusion is given off. The
                                    solidi/Qcation front (solid-liquid interface) moves through the molten metal from the
                                    mold walls in toward the center. The solidified metal, called the casting, is taken out
                                    of the mold and allowed to cool to ambient temperature.
                                        As shown in Fig. 10.1b and described in greater detail in Section 10.5 .2, metals
                                    shrink while cooling and generally also shrink when they solidify (see Table 10.1).





                                   Cooling of liquid                           Shrinkage of solid

                                   Freezing begins
                                                       Freezing     3.
                        U.)                           ends
                        _
                        3    _____             B                     q)
                           \FreeZingA                               Z     Solidification
                             temperature                            123;  Shrinkage
                                                      Cooling of    cn
                                                      solid

                                       Liquid
                           <-Liquid      +          Solid      >                 Shrinkage of liquid
                                       solid

                                            Time                                       Time
                                             (H)                                        lb)

                                    FIGURE |0.l  (a) Temperature as a function of time for the solidification of pure metals.
                                    Note that freezing takes place at a constant temperature. (b) Density as a function of time.















                        Temperat
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