Page 264 - Mechanical Engineer's Data Handbook
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252                                                 MECHANICAL  ENGINEER'S  DATA HANDBOOK

            Natural rubbers                             Polyurethane  adhesives

            Solvent-type natural  rubber  adhesives have  service   These  are  used  for  many  plastics  including  PVC,
            temperatures  up  to 60 "C, and  hot-curing  types are   polystyrene, and melamine. They have good strength
            serviceable up to 90 "C. The former may incorporate   at room temperature, excellent resistance to oils, acids,
            resin for improved strength (see later). Resistance to   alkalis  and  many  solvents,  but  poor  resistance to
            water is  good, but  resistance to oils and  solvents is   water. They give a flexible bond suitable for resisting
            poor. Adherents include: natural rubber; some plastics   shock and vibration.
            such as acrylics and PTFE; expanded natural rubber,
            polystyrene and polyurethane; aluminium alloy, iron   Polysulphide  rubber  adhesives
            and steel; fabrics, card, leather, paper, wood; and glass
            and ceramics. Solutions are used  for car upholstery,   These have  outstanding  resistance to oils, solvents,
            paper,  fabric-backed  PVC  to  hardboard,  and  floor   light, air  and  heat,  and will  bond  steel, aluminium,
            coverings. The latex type is also used to adhere paper   glass,  concrete,  ceramics  and  wood.  Uses  include
            to plastics and metal.  Reclaim rubber  adhesives are   sealants for fuel  tanks,  aircraft  pressure cabins and
            used  for car sound-proofing, draught excluding and   windscreens, lights and pipe joints. With epoxy resins
            undersealing. Pressure-sensitive adhesive is  used  for   they are used  for filling and sealing aluminium roof
            tapes, labels and gluing polythene sheet to metals.   panels and car body panels.
            Polychloroprenes (neoprene)                 Silicone rubber  adhesives

            These  synthetic-rubber-based  adhesives  have  good   These vulcanize at room temperature and bond a wide
            resistance to water, oils and solvents and are either   range  of  materials,  including  silicone  rubber.  The
            solvent  setting  or  vulcanizing  by  heat  curing  or   shear strength is up to 1.4MNm-'  at the maximum
            catalyst with or without resin modifiers. They are used   service temperature of 316 "C. Although the strength is
            for bonding metal, wood, leather, synthetic leather and   not high, they have excellent resistance to high  tem-
            plastics (except PVC) with applications in car, aircraft   peratures. Formulation  with epoxy resin gives good
            and ship-building industries.               strength up to 340°C.
             Acrylonitride butadienes  (nitrile)        6.16.3   Thermoplastic adhesives

             These adhesives are similar to neoprene types and are   In general, these have a low shear strength and suffer
             supplied in the form of solutions for joining rubber to   from creep at high loading. They are therefore used in
             rubber,  unbacked  PVC  to  itself, and  metal,  wood,   low-stress conditions. Resistance is good to oils and
             leather and PVC sheet to metals. The latex type is used   poor to good for water.
             for  PVC  film  to  paper,  textiles, aluminium  foil  to
             plastics, paper and wood, etc. The shear strength is up   Polyvinyl acetate (PVA)
             to 7 MN m-2.
             Butyl  rubber adhesives                    This is  the well-known  'white  glue'  used  for wood-
                                                        working. It also bonds metals, glass, ceramics, leather
             These are used in the car and building industries and   and many plastics. The shear strength is good and the
             are applied by gun or tape. Resistance to water is good,   resistance high to oils and mould, but poor to heat and
             but that  to oils is poor.                 limited to water. Emulsion types are used for ceramic
                                                        tiles. A fast-setting type is available.
             Styrene butadiene rubber adhesives
                                                        Polyvinyl alcohol  (P VA)
             These are based on the synthetic rubber used for car
             tyres and are used in the car industry for bonding felt   This is made from PVA and is similar to it. It is used for
             carpets  and  for  gluing metal  to  rubber  trims.  The   paper  in  a  re-sealable form.  Resistance to  oils  and
             pressure-sensitive type is used for tapes and labels.   greases is good, but poor to water.
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