Page 37 - Mechanics Analysis Composite Materials
P. 37

22                  Mechanics and analysis of  composite materials

             Being a heterogeneous media, a composite material has two levels of heterogeneity.
             The first level represents a microheterogeneityinduced by at least two phases (fibers
             and matrix) that form the material microstructure. At the second level the material
             is  characterized  with  a  macroheterogeneity caused  by  the  laminated  or  more
             complicated macrostructure of the material which consists usually of a set of layers
             with different orientations.
               The first basic process yielding material microstructure involves the application of
             a matrix material to  fibers. The simplest way  to  do it  used  in  the  technology of
             composites with thermosetting polymeric matrices is a direct impregnation of tows,
             yarns, fabrics or more complicated fibrous structures with liquid resins. Thermo-
             setting resin has relatively low viscosity (I 0-100  Pa s) which can be controlled with
             solvents or heating and good wetting ability for the majority of fibers. There exist
             two versions of this process. According to the so-called “wet” process, impregnated
             fibrous material (tows, fabrics, etc.) is used  to fabricate composite parts directly,
             without any additional treatment or interruption of the process. In contrast to that,
             in “dry”  or “prepreg” processes impregnated fibrous material is dried (not cured)
             and thus obtained preimpregnated tapes (prepregs) are stored for further utilization
             (usually  under  low  temperature  to  prevent  uncontrolled  polymerization of  the
             resin).  Machine  making  prepregs  is  shown  in  Fig.  1.16.  Both  processes  having
             mutual  advantages  and  shortcomings  are  widely  used  for  composites  with
             thermosetting matrices.
               For  thermoplastic  matrices,  application  of  the  direct  impregnation  (“wet”
             processing) is limited by relatively high viscosity (about 10l2Pa s) of thermoplastic
             polymer solutions or melts. For this reason, “prepreg” processes with preliminary
             fabricated tapes in which fibers are already combined with thermoplastic matrix are
             used to manufacture composite parts. There also exist other processes that involve
             application of heating and pressure to hybrid materials including reinforcing fibers
             and a  thermoplastic polymer in  the form of  powder, films or fibers. A promising
             process (called fibrous technology) utilizes tows, tapes or fabrics with two types of
             fibers - reinforcing and  thermoplastic. Under  heating and pressure thermoplastic
              fibers melt and form the matrix of the composite material.
                Metal and ceramic matrices are applied to fibers by  means of casting, diffusion
             welding, chemical deposition, plasma spraying, processing by compression molding
             and with the aid of powder metallurgy methods.
                The  second basic  process  provides the  proper  macrostructure  of  a  composite
             material corresponding to loading and operational conditions of the composite part
             that is fabricated. There exist three main types of material macrostructure - linear
              structure which is specific for bars, profiles and beams, plane laminated structure
             typical for thin-walled plates and shells, and spatial structure which is necessary for
             thick-walled and solid composite parts.
                Linear structure is formed by  pultrusion, table rolling or braiding and provides
             high strength and stiffness in one direction coinciding with the axis of a bar, profile
             or a beam. Pultrusion results in a unidirectionallyreinforced composite profile made
              by pulling a bundle of fibersimpregnated with resin through a heated die to cure the
             resin and, to provide the proper shape of the profile cross-section.Profiles made by
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