Page 65 - Methods For Monitoring And Diagnosing The Efficiency Of Catalytic Converters A Patent - oriented Survey
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Robert Bosch GmbH                          47



                   k = constant

                   The deviation M  upstream  of the  catalytic converter  compared to value “1”  is determined.
                   This deviation is positive for lean he1 mixture and negative for rich fuel mixture. The oxygen
                   flow into the catalytic converter  is determined then  as the product  of the  computed  oxygen
                   flow to the engine and the above mentioned 1 deviation.




                   The  oxygen  storage  of the  catalytic  converter  is  defined  as  that  oxygen  quantity  from  a
                   continuous additive oxygen flow being able to be stored by  the catalytic converter from  an
                   oxygen free empty state up to an overflow limit, at which the concentration  of oxygen in the
                   exhaust gas leaving the catalytic converter is above a predetermined value.

                   A simulated downstream value of 1 is then set to “1” for as long as the catalytic converter is
                   disposed in a filling (emptying) state below (above)  an overflow (a depletion) threshold or it is
                   set to the upstream 1 value when either of the thresholds is crossed. The method thus utilizes a
                   model of the temporal behavior of oxygen flows.
                   The method  can be extended  in  measuring the actual 12 value, modifying the defined oxygen
                   storage volume of the  converter  until the  simulated temporal  mean  value of 12 corresponds
                  with the actual 1, value and utilizing the modified oxygen storage volume as a measure of the
                   state of aging of the converter.


                   In DE41 12478 (I 992) a controlled oscillation of the 11 value from rich to lean and vice-versa
                  takes place  (fig. 19a). When the  downstream  probe shows a  significant variation  of 12 (fig.
                   19b,c), then the time integrals of the products of the exhaust gas flow through the catalytic
                  converter times 1, and times 12 are formed:







                      T2





                  As a measure of the performance loss of the catalytic converter,  either the difference between
                  said integrals or the quotient of said difference and one of said integrals is used:
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