Page 183 - Modelling in Transport Phenomena A Conceptual Approach
P. 183

6.3.  CONSERVATION OF ENERGY                                        163

             It should be  remembered that the quantities  CA,  and  JA must be  evaluated at T,,
             whereas p~, epB, Pig  and  SCB  must be  evaluated  at  Tf = (T, + T,)/2.   Since
            T, is unknown,  a trial-and-emr procedure will be  used  in order to detennine T,
             as follows:
             Step 1: Assume T,  = 15°C

             Step 2: Determine  the physical properties:
                                          Prt = 0.01703 bar
                For water at 15°C (288K) :
                                          i~ 18 = 44,388 kJ/ kmol
                                                    x
                                               2466
                                             =
                The saturation concentration is


                           -         0.01703        = 7.11 x    kmol/ m3
                           -
                              (8.314 x 10-2)(15 + 273)

                The fiZm temperature is Tf = (35 + 15)/2 = 25°C.
                                       f p = 1.1845 kg/ m3
                                        v = 15.54 x    m2/ s
               For air at 25 "C (298K) :
                                        Cp = 1.005 kJ/ kg. K
                                        Pr = 0.712
                The diffusion coeficient of water in air is
                         DAB  = (2.88 x  E  (     3'2   = 2.68 x   m2/ s
                                      !
                                    )

                The Schmidt number is
                                           Y
                                     sc = -
                                          DAB
                                       -  15.54 x low6  = 0.58
                                       -
                                          2.68 x 10-5

            Step 3:  Substitute  the values  into Eq.  (7) and  check  whether  the right and  left
            sides  are equal to each other:



                                  2/3   (7.11 x 10-4)(44,388)  0.712  2/3
                                          (1.1845)(1.005)  (058) = 30.4

            Since  the left- and right-hand  sides  of Eq.  (7) are quite different from each other,
            another value of T, should  be  assumed,
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