Page 213 - Modelling in Transport Phenomena A Conceptual Approach
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7.3.  CONSERVATION OF TOTAL MASS                                    193


              2.  Ideal gas behavior.
            Analysis

            System:  Naphthalene  sphere
            The terms appearing in the conservation of species A, Eq.  (7.2-2), are









            Therefore, Eq.  (7.2-2) reduces to





            Taking  CA,  = 0 and rearrangement gives






           where Do is the initial diameter of the naphthalene sphere.
               The average mass transfer coeficient, (ICC),  can be related to the diameter of  the
           sphere,  Dp, by using  one of  the mass transfer correlations given in Section 4.3.3.
            The use of  the Ranz-Marshall  correlation,  Eq.  (4.3-33),  gives

                                     Sh = 2 + 0.6 Reg2 SC”~                     (3)

           a) When air is stagnant, i.e.,  Rep = 0, Eq.  (3)  reduces to




           Substitution  of Eq.  (4) into Eq.  (2) and integration gives






            The saturation concentration  of naphthalene,  CA, , is
                               psot
                                A
                         CAW = -
                               RT
                             -      11.7/760
                             -                   = 5.17 x lo-*  kmol/ m3
                               (0.08205)(90 + 273)
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