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212                               New Trends in Eco-efficient and Recycled Concrete




                                                   Production of  Production of
                                                    fuels and
                                                   electricity  raw materials
                   Production of
                            Production of
                    fuels and  raw materials   Primary  Iron blast
              Primary  electricity            production  furnace     Iron
              production                                           transformation
              Production of  Coal fired       Production of  Slag
                water   power plant   Bottom ash  water  granulation
                                                                      Steel
                                      Electrical
              Treatment              power network  Treatment  Drying
                          Drying
                                       Electricity
                                                       Grinding
                          Stock
                                                         Stock
                          Fly ash                        GBFS

                                           Extraction of raw
                                            materials
                              Primary
                             production
                            Production of fuels  Combustion in the  Si-metal
                              and energy   electric arc oven

                             Treatment
                                              Stock
                                             Silica fume

         Figure 9.1 Schematic overview of primary production and subsequent basic treatment for
         fly ash, blast-furnace slag and silica fume cf. Chen et al. (2010b) and Chen (2009).


          Table 9.2 CO 2 ,SO x ,NO x and dust emissions to be assigned to the basic treatment of 1 kg
          of fly ash, blast-furnace slag and silica fume

          Chen et al. (2010b)  Fly ash (kg)  Blast-furnace slag  Silica fume
          and Chen (2009)

          CO 2
                               2.08 3 10 24
          SO x
                               2.17 3 10 25
          NO x
          Dust                 1.37 3 10 24   2.16 3 10 25  kg   2.16 3 10 25  kg
           This statement no longer holds true when fly ash, blast-furnace slag and silica
         fumes are identified as valuable by-product. Then, part of the impact of the main
         industrial processes, that is, coal-fired electricity, steel and Si-metal production,
         should be assigned to them. As suggested in related literature on environmental
         impact of supplementary cementitious materials (Van den Heede and De Belie,
         2012; Chen et al., 2010b; Chen, 2009) this should be done using a well-defined
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