Page 119 - Origin and Prediction of Abnormal Formation Pressures
P. 119

SMECTITE-ILLITE  TRANSFORMATIONS                                       99
                                                   %

                      20  40  60   20  40  60   20  40  60   20  40  60   20  40  60
                     ,,                          i   i   i   i   i   ;    I   1   1
                     II    9      c ;l  ..       9 "  Cc)
                2000   '   'ca                             o   Cd)           Ce)
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                         o 9          ea
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             E  3000                  ee       1"
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            ..c:  4000                                     oQ
            NI,,,,-       9   eo    9    9   e 9    9   ~Q
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                                   o    9  eee    9        !:          :o
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                      9   9  "   "I:',   "'i|"  :   !t"                oe
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                     e,,    9    9   9    9    9    9    9   QOqS       "~ e  9   9
            Fig. 4-2. Contents of various clay minerals in  the  Productive Unit of the  Baku Archipelago: (a)  mont-
            morillonite, (b)  hydromica, (c)  kaolinite, (d)  chlorite, and  (e)  mixed-layered minerals. (Modified after
            Buryakovsky et al., 1995, fig. 4, p. 206.)
            Fig.  4-1.  On  the  other  hand,  field  data  in  the  South  Caspian  region,  as  discussed  in
            this  chapter,  shows  that  a  practically  unaltered  montmorillonite  is  present  in  the  Baku
            Archipelago  deposits  at depths  down  to  6  km,  i.e.,  throughout  the  entire  drilled  section
            (Fig.  4-2).  This  suggests  a  subordinate  role  of montmorillonite  dehydration  in  the  total
            process  of AHFP  development.



            BURST'S COMPACTION MODEL

               A  compaction  model  based  on  a  three-stage  dehydration  sequence  and  the  transfor-
            mation of montmorillonite  clay to  mixed-layer varieties  was  proposed  by Burst  (1969).
            The  initial  dehydration  stage  is  essentially  completed  in  the  first  few  thousand  feet
            of  burial  as  the  interstitial  water  content  is  reduced  to  approximately  30%  (20-25%
            interlayer  water  and  5-10%  residual  pore  water)  (Fig.  4-3).  During  the  second  stage,
            the  argillaceous  sediment  is  in  a  state  of  quasi-equilibrium  as  it  continues  to  absorb
            geothermal  heat.  Pressure  is  relatively  ineffective  as  a  dehydrating  agent  because  of
            the  increased  density  of  the  interlayer  water packet.  As  soon  as  the  heat  accumulation
            is  sufficient  to  mobilize  the  interlayer  water,  one  of  the  two  remaining  interlayers  of
            bound  water  (statistically  averaged)  is  discharged  into  the  bulk  system.  Burst  (1969,
            p.  80)  stated  that  the  amount  of  water  in  movement  should  constitute  10-15%  of
            the  compacted  bulk  volume.  During  the  third  stage,  the  final  water  increment,  having
            approximately capillary water density,  gradually is forced  out of the clay mineral lattice
            and  voids  as  sediment  temperature  increases.  Burst's  dehydration-compaction  model
            was discussed by Rieke and Chilingarian  (1974).
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