Page 237 - Packed bed columns for absorption, desorption, rectification and direct heat transfer
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                            Table 16. Coefficients of Eq. (116) for all considered systems, for positive and negative ones
                                     Systems   c«             c 3          e 4
                                     All systems  2.552  0.033  -0.239  0.306  0.290  -0.530
                                     Positive*  25.462  -0.0065  -0.439  0.027  1.061  -2.50
                                     Negative*  3.203  0.07H  -0.394  0.387  0.136  2.45
                          * See Chapter 4.



                                  Since the sizes of the investigated packings are very small, the
                          application of Eq. (116) for industrial calculations is not to be recommended.

                          3.2.1.2.1.5. Equation for calculation of the axial mixing coefficients

                          3.2.1.2.1.5.1. Axial mixing in the gas phase
                                  In general, the dispersion of a gas flowing in a packed bed is considered
                          to be a result of two main mechanisms: molecular diffusion and eddy
                          (turbulent) diffusion. At low Reynolds number (ifee<l) the dispersion is
                          controlled by the molecular diffusion. At RgQ>\Q, the turbulent diffusion is a
                          dominant factor. Since all industrial packings operate at rather great values of
                          Re G, the molecular diffusion is not of importance for the axial mixing in the gas
                          phase.
                                  Based on own data for Raschig rings 6-13 mm for the axial mixing in
                          the gas phase, De Maria and White [116] obtained the equations:

                           for dry packings

                           Pea = 1.94,                                                      (117)

                           for irrigated packings


                                                                                            (118)



                           where:

                                                          — - Peclet number for the gas phase;
                           Pe G=Bo G
                                      a.H      s(l-H d).a.D G
                                                                      2
                           D G - axial mixing coefficient for the gas phase, m /s;
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