Page 288 - Petroleum Geology
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            accumulation of  evaporites. This environmental change seems to be due larger-
            ly, if  not entirely, to the growth of the encircling reefs.
              The north-western belt of pinnacle reefs, studied by Gill (1979) and referred
            to in Chapter 9 in the context of differential entrapment, grew on a carbonate
            platform - the Lockport  Formation - and euxinic conditions developed in
            the deeper water in which the Cain Formation accumulated. The Cain For-
            mation is only 7-8  m thick, and consists of a basal dark grey to black argilla-
            ceous mudstone with a mean total organic carbon content of 0.3%, followed
            by  cyclic  calcite and  anhydrite with halite.  .The carbonate components are
            rich in bituminous matter.
              The  reefs  were  dolomitized  and  secondary  porosity  development  made
            them  good  potential  reservoir  rocks.  They  were then  sealed by evaporites.
            The regional  dip  of  the  Lockport  Formation,  on  which the pinnacle reefs
            grew, is less than 2".
              Thus, before the end of the Silurian period  all the ingredients of  a petro-
            leum province existed:  source rock, carrier bed,  cap rocks and stratigraphic
            traps. The size of  the traps, had it not been for subsidence, would have been
            very small because the average basal area of  a pinnacle reef  here is only 0.3
            km2 (Gill, 1979, p. 612); but subsidence gave them vertical dimensions of 90
            to 180 m  at depths  from  900  to 2100 m.  The fluid capacity  of  the reefs,
            even  then,  might  have  been  quite  small had it not been  for the diagenetic
            development of porosities averaging about 6%.
              The source of  the petroleum is clearly not in the reefs themselves because
            the very strong evidence of  differential entrapment and the existence of gas-
            bearing, oil-bearing and water-bearing reefs of the same type indicate the main
            source to be down-dip of  the petroleum-bearing  reefs, and that it generated
            both oil and gas.  The evidence of  migration  and differential entrapment re-
            quires  a  common  carrier  bed  and  a  common source that had more energy
            than  the  carrier  bed  and the deepest reservoir. There may have been other
            contributary  sources in some areas, with these energy relationships to partic-
            ular parts of  a carrier bed and reservoir, but the main source must have been
            in hydraulic continuity with the Lockport Formation. Sharma (1966, p. 347)
            suggested the  underlying  Clinton  Formation  as source  rock  for the Peters
            reef  in St. Clair county, Michigan; but Gill (1979, p.  618) pointed out that
            it does not appear to be in a favourable facies in positions that satisfy the re-
            quirements  for  the  main  source,  while  the  Cain  Formation  overlying the
            Guelph and Lockport Formations does.


            DEVONIAN REEFS OF WESTERN CANADA

              The prolific  and widespread reefs of  the Silurian Period  were followed in
            the  Devonian  Period  by  perhaps  even  more  prolific  and  widespread  reefs
            around  the  world  (although  they were, perhaps, more concentrated during
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