Page 66 - Petroleum Geology
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45

            proportional to thickness when compaction  is due to gravity without lateral
            spreading. The immense volumes of  water expelled will be appreciated when
            it  is  considered  that  1 km3 of  water-saturated  mudstone  compacted from
            30% porosity to 12.5% porosity expels 0.2 km3 of water. This is equal to the
            total pore volume of  1 km3 of sandstone with 20% porosity. This is why there
            are difficulties with the concept of connate water (pp. 77-78).  The chemistry
            of  mudstone pore water  may differ considerably from that of the displaced
            sandstone pore water. By  the same token, if  this water cannot escape from
            the mudstone (or, indeed, from an intercalated sandstone) considerable quan-
            tities are retained and buried to greater depths and higher temperatures for a
            longer time.
              Mudstone compaction, like other sediment compaction, involves chemical
            and physicochemical processes as well as the physical, but these are not suf-
            ficiently well understood yet for general rules to be formulated. In confining
            ourselves to the physical processes, however, we believe that these are suffi-
            cient to explain the observed and deduced effects and that it is a valuable -
            even essential - simplification.
              The  matter of  mudstone compaction as a function of  depth, overburden
            load  and  bulk  densities,  has  been  the  subject  of  several studies  (Hedberg,
            1926, 1936; Athy,  1930a; Dickinson,  1951, 1953). Hedberg’s  (1936) and
            Athy’s curves (Fig. 3-2) differ from each other in some interesting respects,
            but we cannot claim to understand these differences fully.
              First, it is essential to understand  clearly the nature of such curves. They
            are, of  course,  a  plot  of  present porosity  (or wet bulk  density, as the case


                      POROSITY  f
                              7
                                -
                                    7
                                   -
                                 v
              0 7-7  -I--
             km                    ’  ,
                                    /
                                  /

            W



                                         5



              *LI   I                XlOOOft
            Fig.  3-2. Mudstone compaction  curves  of  Athy  (1930) and  Hedberg (1936), the latter
            generalized.
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