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Stability and Tempco Issues

            164   Chapter Eight


                            Weakly
                            absorbing        R L
                            liquid
                                            + A
                                            -
                                        PD
                        LED
                        Source  Cuvette
                        Figure 8.1 Measurement of small, slow
                        changes in transmission represents one
                        of the most difficult measurements.



                        so that 1mW of the source light reaches the photodiode and receiver. At this
                        wavelength the photodiode’s responsivity is only 0.15, but nevertheless we have
                        150mA of photocurrent. A resistor of 33k delivers almost 5V output from the
                        transimpedance amplifier, and the design is shot-noise limited. The LED is mod-
                        ulated at 10kHz, well away from interfering line-voltage harmonics and the
                        low-frequency 1/f noise increase. With 150mA photocurrent the shot-noise
                                                               -7
                        limited precision (DI/I) should be about 10 in a 1Hz bandwidth.
                          It is instructive to build such a simple system, connect it to a data-logger, and
                        run it over a period of a few hours. Initially the performance may be awful, as
                        the tiny battery you chose to run the LED dies after a few minutes, the double-
                        sided adhesive tape holding the photodiode falls off, and the cuvette walls
                        become covered in bubbles out-gassing from the liquid. After these oversights
                        have been remedied, in any but the stablest of environments, the detected signal
                                                                        -7
                        can still be expected to vary by much more than 10 , for example by several
                        percent, primarily due to changes in component parameters with temperature
                        variations.


            8.2.1 Load and bias resistors
                        The photoreceiver’s detection gain is largely unaffected by changes in opamp
                        characteristics. As long as AC measurements are made at a frequency where
                        closed loop gain is still high, the open loop gain and the amplifier offset volt-
                        ages play only a small role. The bulk of the precision of the circuitry rests with
                        the feedback components. The most obvious source of error is therefore the
                        transimpedance R L. Output voltage is linearly proportional to it, and all resis-
                        tors change their resistance with temperature. Described by the relative tem-
                        perature coefficient of resistance, or “tempco” (1/RdR/dT), and conveniently
                                                   -6
                        given in units of ppm/°C (10 /°C), this parameter depends on the fabrication
                        process. Some types of low cost carbon resistors exhibit a tempco of ±250ppm/°C
                        or worse. Hence for a 50°C temperature fluctuation in the component, a com-
                        bination of ambient temperature variation, enclosure heating due to electronic
                        dissipation, and self-heating in the resistor, we can expect a sensitivity varia-
                        tion of ±1.25 percent over the temperature range. The LED bias resistor suffers


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