Page 139 - Principles of Applied Reservoir Simulation 2E
P. 139

124  Principles  of Applied  Reservoir  Simulation


        yields a black oil. If we monitor methane content (C,), we see that  it tends to
        decrease as fluids change  from  dry gas to black oil.
                                    Table 13-2
                Typical Molar Compositions  of Petroleum Fluid Types
                            [after Pedersen, et al.,  1989]

         Component      Gas     Gas Condensate   Volatile Oil  Black Oil
                           0.3             0.71          1.67        0.67
         N 2
                           1.1             8.65          2.18        2.11
         C0 2
         C,               90.0            70.86        60.51        34.93
                           4.9             8.53          7.52        7.00
         C 2
         €3                1.9             4.95         4.74         7.82
                           1.1             2.00          4.12        5.48
         iC 4+nC 4
                           0.4             0.81          2.97        3.80
         iC 5+nC 5
                       C 6+: 0.3           0.46          1.99        3.04
         iC 6+nC 6
                                           0.61         2.45         4.39
         C 7
                                           0.71         2.41         4.71
         C 8
                                           0.39          1.69        3.21
         C 9
                                           0.28          1.42         1,79
         C 10
         c,,                               0.20          1.02         1.72
                                           0.15     C !2+:5.31        1.74
         C 12
                                           0.11                      1.74
         C 13
                                           0.10                      1.35
         C 14                              0.07                      1,34
         C ss
         c,;                               0.05                      1.06
         CP                           C 17+:  0.37                   1.02
         v-qg                                                        1.00
                                                                     0.90
          1 9
                                                                 C 20.:9.18
         ^20
                                13.2 Fluid  Modeling
             In general, fluid behavior is best modeled using an equation of state. Table
        13-3  shows  some  cubic  equations  of  state  (EoS)  used  in  commercial  com-
        positional simulators.  In addition to pressure (P), volume  (V), and temperature
        (T),  the EoS contains the gas constant R and a set of adjustable parameters  (a,
        b}  which  may be functions of temperature. The EoS in Table  13-3  are called
        "cubic" because they yield a cubic equation for the compressibility factor Z  =
       PVIRT.  In the case of an ideal gas, Z -  1.
   134   135   136   137   138   139   140   141   142   143   144