Page 116 - Process simulation and control using Aspen
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106      PROCESS SIMULATION AND CONTROL USING ASPEN        1

               In the CSTR model, ketene is decomposed producing carbon monoxide and
                ethylene gas.
                                                K '
                                        CH2CO-> CO + 0.5 C2H4
                where,
                                               , 1 .5


                                       rk = K '
                                     -
                                                       26586
                                       K= exp 22.8-            mol/lit s . atm 15
                                                         T
                                                        25589
                                      K'  = exp 19.62-          mol/lit . s

                                [C,] basis = Partial pressure

                Here, -rA is the rate of disappearance of acetone (A), -rk the rate of disappearance
                                                                             '
                of ketene ik), PA the partial pressure of A, and K and K the reaction rate
                constants. Pure acetone feed with a flow rate of 130 kmol/hr enters the reactor
                at 7250C and 1.5 atm. The reactor with a volume of 1    .4 m3 operates at 700oC
                and 1.5 atm. Applying the SYSOPO base method , compute the component mole
                fractions in the product stream .

                                             REFERENCE |


                 H. Scott (2005), Elements ofChemical Reaction Engineering , Prentice-Hall of India
          Fogler ,
             3rd ed.. New Delhi
                                .
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