Page 166 - Refining Biomass Residues for Sustainable Energy and Bioproducts
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138                     Refining Biomass Residues for Sustainable Energy and Bioproducts


                                       Primary source
                     Biomass(lignocellulosic)       Fossil fuels
                  Biocatalytic process
                                                      Chemo-catalytic process
                       Biorefining process
                    (separation and hydrolysis)    Oil extraction


                        Fermentation
                                                     Refinery


                     Crude and intermediates
                                                  Crude chemicals

                      Downstream processing
                                               Gasoline  Ethylene

                   Filtration/distillation/dehydration



                     Fine chemicals (C 5 ,C 3 ,C 2 )

         Figure 6.1 Production of chemicals both by biological and fossil route with system
         boundaries.


         process also effectively helps in the production of functional chemicals at low capi-
         tal cost (Sanders et al., 2007; Marquardt et al., 2010). The production of chemicals
         both by biological and fossil routes represented with system boundaries is shown in
         Fig. 6.1.




         6.3.2 Bio-based chemicals
         Collection and processing of biomass are the main criteria for bio-based chemicals.
         Biomass is obtained from food factories, waste stream, and also from residues of
         agricultural area. The most challenging part lies in conversion of complex mole-
         cules to small and single molecules. The obtained single molecules are further pro-
         cessed to value-added products at low cost and minimal energy inputs. The biomass
         components are either converted into homogeneous or heterogeneous components,
         depending upon the products of interest. In order to reduce the capital cost during
         transportation of biomass and processing, BioLiq method was used, in which pri-
         mary pretreatments were carried close to the field. The purity of the feedstock
         raises a serious attention as these types of biomass consist of complicated and vari-
         able networks. The introduction of chemical networks has gained lot of importance
         as they mainly work based on the organizational principles to yield high-quality
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