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The Electronic System
                                                                m
                                                                   ,
                                                                  θφ)
                             part are the spherical harmonic functions Y (
                                                                       (see Table 2.2). The
                                                                l
                                                          ⁄
                                                                          r
                                                        r
                             radial functions are  Rr() =  R () r  , where the  R ()   follow a dif-
                                                                        ,
                                                      ,
                                                     nl                 nl
                             ferential equation of Laguerre type, and are shown in Figure 3.9• for dif-
                             1


                             1 1 1              1




                                      5 5




                             1                  1                   1







                Figure 3.9. The radial wavefunction R ()   for different   and  . l
                                                 r
                                                              n
                                               ,
                                              nl
                             ferent  nl,(  )  . The wavefunction ψ  ( r θφ)   (see Table 3.1) has three
                                                             ,,
                                                         ,,
                                                        nlm
                             integer parameters:
                             • n  : the quantum number of radial motion,
                                         ,
                                    ,,
                                            –
                             • l =  01 … n 1   : the first quantum number of angular motion,
                                         ,
                                      ,
                             • m =  – 1 … 1  : the second quantum number angular motion
                               (note that  m   is an integer, not to be confused with the mass of the
                               electron).
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