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Electron-Photon
                           E a)                 b)                  c)
                             2
                                                         1 photon   1 photon
                           E                                                  2 photons
                            1



                Figure 7.10.  Electron-hole recombination. a) Non-radiative (without photon emission)
                recombination. The energy is dissipated into other degrees of freedom, e.g., phonons. b)
                Spontaneous emission of a photon. c) Emission is stimulated by an incoming photon that
                is in phase with the stimulation.



                             The energy levels of the respective states are  E  1   and  E  2  , which means
                                                                     ⁄
                             that the electromagnetic wave at ω =  ( E –  E ) —   couples resonantly
                                                         0
                                                                   1
                                                               2
                             to the electronic system. We insert this into the equation of motion for the
                             superposition coefficients as given from (3.74) in first order perturbation
                             theory to give
                                                   i –
                                           c˙ t() =  ----V c t()exp (  i – ω t)
                                            1        12 2         0
                                                  —
                                                                                  (7.82)
                                                   i –
                                           c˙ t() =  ----V c t()exp ( iω t)
                                            2        21 1        0
                                                  —
                Rotating     Remember that  V   has a harmonic time dependence through the elec-
                                           mn
                Wave         tric field vector with frequency  , near the resonance frequency ω 0  . Let
                                                      ω
                approxi-     us assume that c t()   and c t()   change very slowly on time scales where
                mation                    1       2
                             exp ( − i + ω +(  ω )t)   is changing. Integrating (7.82) over time will yield a
                                        0
                             vanishing contribution of the exponential term since it will perform many
                             oscillations in the integration period that cancel each other. Therefore, we
                             are led to neglect the terms with the summed frequencies  ω +(  ω )   in the
                                                                                0
                             exponents compared to those with the frequency difference  ωω )  .
                                                                               (
                                                                                  –
                                                                                     0
                             This so called rotating wave approximation yields for the transition
                             dipole matrix element the new form  V  =  µexp (  i – ωt)E ⁄  2  , where
                                                             12              0
                             µ   is the projection of the dipole matrix element  µµ µµ   along the electric
                                                                      12
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