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Numerical  Methods   77

                     Another possible  form is  the exponential function

                     F(t) = aeP‘

                   and although partial differentiation will produce two equations in two unknowns,
                   they will be nonlinear and cannot be written in matrix form.  However, a change
                   in  variable  form  may  produce  a  model  that  is  linear,  for  example,  for  the
                   preceding  equation

                     In  (F) = In  (a) +  Pt

                   and if  X is defined to be t, Y  to be In  (F), a,  = In  (a), and a, = j3,  the equation
                   becomes

                     Y(x) = a,, + a,X

                   and linear least  squares analysis  may  be  applied.
                     In  order  to  determine  the  quality  (or the  validity) of  fit  of  a  particular
                   function to  the  data points given, a  comparison  of  the  deviation of  the  curve
                   from the data to the size of the experimental error can be made. The deviations
                   (i.e.,  the  scatter off  the  curve) should be  of  the  same order  of  magnitude  as
                   the  experimental error, so that  the quantity “chi-squared’’ is  defined  as






                   where y,’ = is  the fitted function and y, is  the measured value  of y  at xl, so that
                   Ay,  is  the  magnitude  of  the  error  of  y,’.  The  sum  is  over  n  points  and  if  the
                   number  of  parameters in  the  model function  is  g,,  then if  0 (X’)  > 0 (n - g),
                   the approximating function is a poor fit, while if  0 (X2) < 0 (n - g), the function
                   may  be  overfit, representing noise  [lo].
                     The simplest form of approximation  to a continuous function is some polynomial.
                   Continuous functions may be approximated  in order to provide a “simpler form”
                   than the original function. Truncated power  series representations (such as  the
                   Taylor  series) are one class of  polynomial  approximations.
                     The Chebyshev polynomials, T,(x) or Tn, which  exist on the interval -1  I x I 1,
                   form the series

                     To  =  1
                     T,  = x





                   (see Table  1-14 for  a  more  complete  list). If  these  polynomials  are  inverted,
                   powers of  x are given in  terms of T,(x) (Table  1-15). Any  finite interval  a I y  I b
                   can be  mapped  onto the interval -1  I x  I 1  by  the formula

                     x  = (2y - b  - a)/(b  - a)
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