Page 92 - Standard Handbook Petroleum Natural Gas Engineering VOLUME2
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80   Reservoir Engineering

























                                                             I  WATER-WET
                                       OIL- WET
                                      s,,   =  10% PV

                                                            I
                                                            I
                                                            I
                                                        I    I    I    I    I
                               0        20        40        so        80       100
                                    OIL  RECOVERY,  *lo  OIL  IN PLACE
                   Figure 5-56.  Comparison of oil recovery for oil-wet and water-wet cores [133].

                   and  several investigators have  suggested better  oil  recovery  from  cores  of
                   intermediate or mixed wettability [ 106,108,121,123,171]. More recent evidence
                   by  Morrow  [172]  and Melrose and Brandner [173]  suggests that mobilization
                   of  trapped oil is more difficult in  the intermediate wettability region, but the
                   prevention of  oil  entrapment  should be  easier for  advancing contact angles
                   slightly less than 90".
                     With water-wet cores in laboratory waterfloods, the  oil production at water.
                   breakthrough  ceases abruptly  and water  production  increases sharply. With
                   systems that are not water-wet, water breakthrough may occur earlier, but small
                   fractions of  oil are produced for long periods of  time at high water  cuts. In
                   strongly water-wet systems, the residual oil that is permanently trapped by  water
                   resides in  the  larger pores, whereas in  oil-wet  systems trapping occurs in  the
                   smaller capillary spaces [106,133].
                   Relatlve Permeability Characteristics. For  a system  having a strong wetting
                   preference for either oil or water, relative  ermeability of  the wetting phase is
                   a function of  fluid  saturation only [76,13{,160].  Details of  the  effect of wet-
                   ability on relative permeabilities have  been discussed by  several authors [llS,
                   135,174,1751.  In a detailed study using fired Torpedo (outcrop sandstone) cores,
                   Owens and Archer [174] changed wettability by  adding surface active agents to
                   either the oil or water.  Firing of the cores stabilized any  clay minerals present
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