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14   Cha p te r  T w o


                     Programming) methods. Hybrid methods have also been proposed;
                     these approaches incorporate heuristic rules as well as Mathematical
                     Programming (MPR). Much as with any decision making, process
                     synthesis (or design) is an activity for which no past experience can be
                     ignored, especially when it comes to localized details of the design.
                     The most popular approach is to create a superstructure for the
                     network being designed and then choose the best possible solution
                     network from the superstructure options.

                2.4   Pinch Technology and Targeting Heat Recovery:
                      The Thermodynamic Roots
                     Furman and Sahinidis (2002) have compiled a comprehensive review
                     of works tracing the development of the research on HENs in time.
                     Their study shows that there was only mild interest in heat recovery
                     and energy efficiency until the early 1970s, by which time just a few
                     works in the field had appeared. But between the oil crises of 1973–
                     1974 and 1979 there were significant advances made in HI. Although
                     capital cost remained important, the major focus was on saving
                     energy and reducing related costs. It is exactly this focus that
                     resulted in attention being paid to energy flows and to the energy
                     quality represented by temperature. The result was the development
                     of Pinch Technology, which is firmly based on the first and second
                     laws of thermodynamics (Linnhoff and Flower, 1978).
                        In this way HEN synthesis—one of the most important and
                     common tasks of process design—has become the starting point for
                     the PI revolution in industrial systems design. HENs in industry are
                     used mainly to save on energy cost. For many years the HEN design
                     methods relied mostly on heuristics, as necessitated by the large
                     number of permutations in which the necessary heat exchangers
                     could be arranged. Masso and Rudd (1969) is a pioneering work that
                     defines the problem of HEN synthesis; the paper proposes an
                     evolutionary synthesis procedure that is based on heuristics. An
                     alternative HEN synthesis method is described in Zhelev et al.
                     (1985), one that exploits synergies between heuristics and
                     combinatorics. In this approach, several suboptimal networks are
                     synthesized, and in most cases they are less integrated (consist of
                     more than one subnetwork). A complete timeline and thorough
                     bibliography of HEN design and optimization works is provided in
                     Furman and Sahinidis (2002). The paper covers many more details,
                     including the earliest known HEN-related scientific article: Ten
                     Broeck (1944).
                        The discovery of the Heat Recovery Pinch concept (Linnhoff
                     and Flower, 1978) was a critical step in the development of HEN
                     synthesis. The main idea behind the formulated HEN design
                     procedure was to obtain—prior to the core design steps—guidelines
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