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P r o c e s s I n t e g r a t i o n  19


                     retrofits, both water and combined water-and-energy minimization,
                     as well as to minimize total site energy consumption—a process
                     that includes Combined Heat and Power, locally integrated energy
                     sectors, integration of renewables and waste-to-energy techniques,
                     and combinatorial tools (P-graph and S-graph; see Chapter 7). In
                     addition, recent applications have extended the PI approach to
                     regional energy and emissions planning, financial planning, batch
                     processes, and the targeting of other constrained resources, such as
                     land, renewable energy, and emissions. In the wake of the initial
                     breakthrough of Pinch Analysis for HEN synthesis, all these new PI
                     applications follow the same simple logic: target setting should
                     precede designing. In the most straightforward cases—such as HEN
                     synthesis for Maximum Energy Recovery (MER) and water network
                     synthesis for maximum water reuse—the targets can be interpreted
                     as indicators of what a rigorous application could actually achieve.
                        However, the applicability and benefits of PI are not limited to
                     these straightforward cases. In fact, the target setting can be applied
                     in various contexts and still yield enormous benefits in terms of
                     reduced computational and project development time. Klemeš,
                     Kimenov, and Nenov (1998) described several applications of Pinch
                     Technology within the food industry, work that was further
                     developed in Klemeš et al. (1999). This research showed that Pinch
                     Technology can provide benefits far beyond oil refining and
                     petrochemicals.
                        The most important property of thermodynamically derived
                     heat recovery targets is that they cannot be improved upon by any
                     real system. Composite Curves play an important role in process
                     design; for HEN synthesis algorithms, they provide strict MER
                     targets. For process synthesis based on MPR, the Composite Curves
                     establish relevant lower bounds on utility requirements and capital
                     cost, thereby narrowing the search space for the following
                     superstructure construction and optimization.
                        The preceding observation highlights an important character-
                     istic of process optimization problems, and specifically those that
                     involve process synthesis and design. By strategically obtaining
                     key data about the system, it is possible to evaluate processes based
                     on limited information—before too much time (or other resources)
                     are spent on the study. This approach follows the logic of oil
                     drilling projects: potential sites are first evaluated in terms of key
                     preliminary indicators, and further studies or drilling commence
                     only if the preliminary evaluations indicate that the revenues
                     could justify further investment. The logic of this approach
                     was systematically formulated by Smith in his books on PI for
                     process synthesis (Smith, 1995; Smith, 2005) and by Daichendt and
                     Grossmann (1997), whose paper integrated hierarchical decom-
                     position and MPR to solve process synthesis problems.
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