Page 91 - Materials Chemistry, Second Edition
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                    Sustainable Industrial Design and Waste Management
                72
                       system. The evaporated hexane is recovered within the system and
                       reused.
                     • Purification of oil: During this stage oil is purified by removing all
                       impurities such as color, odor, fatty acids, gums, and residual soap. This
                       step takes place in the following stages:
                       – Degumming to remove about 0.15% gums.
                       – Neutralization using caustic soda to remove fatty acids to generate
                          soap stock 5%.
                       – Washing and separation by centrifuge.
                       – Drying and bleaching to remove the color.
                       – Deodorization of the bleached oil by vacuum distillation.
                     • Packaging of the final product: A brine chiller is used to cool the
                       refined, bleached, deodorized oil in a buffer tank. Then the final product
                       is transferred to 0.75 liter or 2.0 liter bottles, capped, labeled and cased.


                CP opportunity assessment
                Cleaner production opportunities were identified during the industrial audit
                of the factory in order to achieve maximum conservation of raw materials
                and energy. The following are some of the identified cleaner production
                opportunities (SEAM 1999c):

                     • High amounts of steam losses due to the bad condition of the steam
                       lines regarding insulations and valves. These losses were estimated
                       to be 34 ton/day.
                     • In the seed receiving unit, broken seeds and hulls are treated as wastes,
                       rather than being reused in the oil extraction process.
                     • Heavy oil leaks and spills occurring during delivery and transfer in the
                       receiving area account for 2–5% of total fuel consumption.


                CP techniques implemented
                     • Good housekeeping: This technique of cleaner production was uti-
                       lized in this case study in the form of a preventive maintenance pro-
                       gram with a total implementation cost of $2,630. The preventive
                       maintenance program included in-factory servicing of the expeller
                       and modification of the packing of the cooling tower, and it has
                       resulted in annual savings of $4,386 and $880 respectively.
                     • Process modification: Process modification was implemented in this
                       case study via modifying and redesigning the production process to
                       allow for the more fresh seeds to be fed into the expeller with a total
                       implementation cost of $1,750. This was achieved by converting the
                       path of the recycled sunflower seed fines from the expeller (original
                       design) to the extraction plant (modified design). As a result, the capac-
                       ity of the expeller has been increased by 40 ton/day of sunflower lead-
                       ing to an annual saving of $21,050.
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