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4.  Genetic Classification of Petroleum Systems   77


             The  genetic  potential,  which  is a  semiquantitative   facies, a general knowledge  of paleogeography,  source
           measure of source rock richness, is defined as the S1 + Sz   rock depositional  models  (Demaison  et  al.,  1984; Jones,
           yield  from  Rock-Eva!  pyrolysis  (Espitalie et  al.,  1 9 77).   1987), and  possible  thickness  changes (e.g., derived from
           The 51 represents the kilograms of hydrocarbons that are   seismic  data)  allow an interpreter to  determine  whether
           thermally distilled from 1  t of rock, and the Sz represents   the  source  rock  in  the undrilled  area  is  likely to  have
           the kilograms  of  hydrocarbons  that  are  generated  by   shown a higher  or  lower SPI than  those obtained  from
           pyrolytic degradation of  the  kerogen in  1  t  of rock   nearby  wells or measured  outcrop  sections.  Therefore,
           (Espitalie et  al.,  1977;  Peters, 1986). Using Rock-Eva!   SPI  calculations  often  serve to constrain the  possible
           pyrolysis  data  of closely spaced whole-rock samples   lateral changes in quantitative source rock potential.
           (approximately every  10 m) in a given well or measured   The concept  and  calculations  necessary  to  formulate
           outcrop section, the average genetic potential for a source   cumulative  hydrocarbon potential,  which we  have
           rock  is determined  in the following manner.  Using drill   renamed SPI for practical reasons, were first applied by
           depth,  the top  and  bottom of the gross source rock   Tissot et al. (1980) to show the variability in hydrocarbon
           interval  are  determined  using a geochemical log (see   source potential of Cretaceous  black  shales in Atlantic
           Figures 5.4-5.11 ,   Chapter 5, this volume). Within this   basins.  Identical calculations were later expanded  to  a
           gross interval, we determined the individual source rock   global geochemical data base by Demaison (1988) and
           interval(s)  on which  the  average  genetic potential is   Demaison and Huizinga (1989). The original purpose for
           calculated.  Within each  source rock  interval,  the  51  +  Sz   developing an SPI data base was to create the operational
           value  for  a  depth  (core)  or depth interval  (cuttings)  is   recognition that source rock  volume,  which  is in  part  a
           multiplied by  the  depth  interval to the  next  deeper   function of thickness,  is  as  important  as source rock
           sample or the sample depth interval, whichever situation   richness.
           applies,  to  get  the  genetic potential rectangle.  We   Our concept  of SPI is  different  from the  "source
           calculate as many genetic potential  rectangles  as   potential rating index" proposed by Dembicki and Pirkle
           necessary to get through the  net  source  rock  interval.   (1985). Their parameter  is calculated by multiplying the
           Then,  the genetic potential rectangles are summed and   average total organic carbon (TOC) content of the source
           divided by the thickness of the net source rock interval to   rock,  the thickness of mature  source  rock,  and  certain
           get the average genetic potential.                maturity scaling factors. Although  the  method  of
             For  source  rocks  that are immature across  an entire   Dembicki and  Pirkle  (1985) can be useful  for mapping
           area,  the acquisition of  SPis  fulfills no useful purpose   regional trends from a given source rock in a well-known
           because hydrocarbon generation has never taken place in   basin, it is  not  suited  for  making  valid  comparisons  of
           the  subsurface. SPI calculations for a given source rock   different source  rock  sections  from basins  around  the
           have relevance only where a thermally mature source   world because it does not take the variability  of kerogen
           rock  has  been  identified.  The  well  penetrations  or   types into account. In contrast, our SPI ranking scale has
           measured  outcrop sections selected for  SPI determina­  been developed for the primary purpose of making these
           tion should be located within or immediately adjacent to   global comparisons. We have made the ranking of very
           the pod of mature source rock. Since SPI is a measure of   different  source rocks  possible by  using  petroleum
           petroleum  potential,  the  magnitude  of SPI  at a given   potential, rather than relative units of effectively realized
           location is optimal when the source rock is immature to   generation, and by expressing  source  rock richness  in
           early mature.  A source rock that has reached a  "middle   terms  of the  genetic  potential (i.e., Rock-Eval  51  +  5 2
           oil  window rank"  or  higher  maturity  shows  a signifi­  yield) rather than TOC.  Our use of the genetic potential
           cantly reduced SPI because the average genetic potential   instead  of  TOC  allows for  a  fundamentally viable
           is depleted due to oil expulsion. In certain cases, theoret­  ranking  of the petroleum potential  of diverse source
           ical  estimates of the  initial SPI  of a mature source rock   rocks containing dissimilar kerogen  types. Thus, a lean
           prior  to maturation can be calculated using the  average   gas-prone source  rock  containing  type  III  kerogen but
           genetic  potential  from  an  equivalent organic facies   having substantial thicknesses (e.g., Tertiary sequence of
           located  in an area where it  is less mature. At a  given   the  Niger  delta  or  Jurassic  source  rock  of  the
           location, the difference between the initial SPI (when the   Barrow-Dampier basin)  can be compared on the  same
           source rock was immature) and present-day residual SPI   SPI ranking  scale  to  oil-prone source  rocks  containing
           (source rock is  mature)  can  provide a rough estimate of   type I or II kerogen and having lower stratigraphic thick­
           the amount of oil expelled  from  the column of source   nesses  (e.g.,  Upper  Jurassic-Lower Cretaceous  source
           rock under 1 m2 (in metric tons HC per square meter).   rocks of the North Sea). SPI can also be used for mapping
             Each SPI is usually obtained from an individual explo­  regional  variations  in a given  source rock,  as discussed
           ration well or  measured  outcrop  section; thus, the   elsewhere.
           resulting value is  representative of the source unit at a
           specific location in the area of interest. Some source rocks   Applications of SPI to Exploration
           show nearly  uniform  richness  and  thickness over long
           distances.  Therefore, an SPI determined for an immature   A  relative  source rock ranking system  has  been
           source rock in one area  is representative  of the original   developed by compiling  the average SPis of individual
           SPI of a thermally mature, lateral equivalent of the same   source rocks from various basins (Figure 4.3; Table 4.1).
           source  rock.  Although  many other  source  rocks  show   For each  source rock, the result listed  in Table 4.1  has
           significant  lateral  variations  in  thickness and  organic   been determined by calculating SPI at as many locations
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