Page 320 - The Tribology Handbook
P. 320

c5                     Solid lubricants and coatinas




               D  BONDED  COATINGS                                                                          a
                 MoS,  resin  coatings  show  performance  trends  broadly  similar to  those      FAILURE   Z-
                                                                                                            0
               for burnished  films but  there  is less dependence of wear life upon relative               i-  u
               humidity.                                                                                    K
                                                                                                            LL
                 Both the coefficient of friction and the wear rate of the coating vary with   E            U
                                                                                                            0
                                                                                                            z
               time.                                                             W                          c
                                                                                                            w
                                                                                 3                          u
                 Laboratory testing is frequently used to rate different coatings for particular      I     L
                                                                                                            W
               applications. 'The most common tests are:                                                    LL
                                                                                                            0
                                                                                                            0
                                                                                           TIME
                                        6
               +           c
               N           W

              Falex (adopted       Pad-on-ring         Oscillating         Thrust washer       Ball on flat
              for                  (Timken and         plain bearing                           (may be 3
              specification        LFW-1                                                       balls)
              tests)
                 It is essential  to coat  the moving surface. Coating both surfaces usually increases  the wear  life, but  by  much less than
                100% (&  30% for plain  bearings,   1%  for Falex  tests). Considerable variations in wear life are often found in replicate
               tests  (and service  conditions).
                                                                   Performance of MoS,  bonded coatings at elevated tem-
                                                                 peratures is greatly dependent on the type of resin  binder
                                                                 and on the presence of additives in the formulation. Typical
                                                                 additives include graphite, soft metals  (Au, Pb, Ag), lead
                                                                 phosphite, antimony trioxide, and sulphides ofother metals.
                                             SOREVIMIN
                                                                 General characteristics of MoS,  films
                                                                 with different binders
                                                HARDENED STEEL
                                                                            Curing   Max.     Adhesion   Relatiue
                                                                            temp.
                                                                   irype    for Ihr           to      wear
                                                                                                      l$e  *
                                                                            ("CI     ("C)     substrate
                                                                   Acrylic   20      65       Fair     7
                      MOS2  \ \ MOS?
                           \\EPOXYRESIN   \  1\                    Cellulose   20    65       Fair    25
                                                                   Alkyd    120      95       Good     1
                                                                   Phenolic   150    150      Good     75

                                                                   Epoxy    200      200      Excellent   18
                             SILICATE BINDER                       Silicone   250    300      Fair     7
                                                                   Silicates   20    450      Fair     50
                                     SILICATE  BINDER              Vitreous   300-600   550   Good     50

                                                                     * Based on simplified laboratory tests.
                           I      I      I      I      I
                           100   200    300    400    500        Points to note in design
                                    TEMPERATURE,  OC
                                                                 1  Wide  variety  of  types  available;  supplier's  advice
                                                                    should always be sought.
                                                                 2  Watch effect of cure temperature on substrate.
                                                                 3  Use acrylic binders on rubbers, cellulose on wood  and
                                                                    plastics.
                                                                 4  Substrate pretreatment  essential.
                                                                 5  Fluids usually deleterious to life.
                                                           c5.3
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