Page 98 - Bird R.B. Transport phenomena
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§3.5  The Equations of Change in Terms of the Substantial Derivative  83

                           corresponds, in Eq.  0.3-8, to equating  the cross-product  terms  and  the internal  angular
                           momentum terms  separately.
                              Eq.  3.4-1  will be referred  to only  in Chapter 7, where  we indicate  that  the macro-
                           scopic angular momentum balance can be obtained  from it.


     §3.5  THE EQUATIONS       OF CHANGE     IN TERMS
           OF THE   SUBSTANTIAL      DERIVATIVE

                           Before  proceeding we point  out  that  several  different  time  derivatives  may be  encoun-
                           tered in transport phenomena. We  illustrate these by a homely example—namely,  the ob-
                           servation  of the concentration of fish in the Mississippi  River.  Because  fish  swim  around,
                           the fish concentration will in general be a function of position  (x, y, z) and time (f).

      The  Partial Time Derivative dldt

                           Suppose we stand  on a bridge  and  observe  the concentration of fish  just  below us as a
                           function  of time. We  can then record the time rate of change of the fish concentration at a
                           fixed  location. The result is (dc/dt)\ ,  the partial derivative  of с with  respect to t, at con-
                                                        xyz
                           stant x, y, and z.
      The  Total Time Derivative  dldt

                           Now suppose  that we  jump into a motor boat and speed  around on the river,  sometimes
                           going  upstream, sometimes  downstream, and sometimes  across  the current. All the time
                           we  are  observing  fish  concentration. At any  instant, the time  rate  of change  of the ob-
                           served  fish  concentration is
                                          dc  =  (dc\  dxfdc)   + d l(dc\    dz(dc)           ( 3 5 1 )
                                          dt  U/,.y,   dt \dx)  +  dt  U y L  dt Ы*,у,<
                                                    2         yAl
                           in which  dx/dt,  dy/dt,  and dz/dt  are the components of the velocity  of the boat.

      The  Substantial Time Derivative D/Dt

                           Next we climb  into a canoe, and  not  feeling  energetic, we just  float  along  with  the cur-
                           rent, observing  the fish  concentration. In this situation the velocity  of the observer  is the
                           same as the velocity v of the stream, which has components v  v , and v . If at any instant
                                                                                       z
                                                                                y
                                                                              x/
                           we report the time rate of change of fish concentration, we  are then giving
                                        DC   dC  ,  dC  ,  „  dC  ,  dC  Dc  dC  ,  (  «  v     ,~  c  о ч
                                           =
                                         Dt H  +  v *~di  + v >4  +  v *~di  o r  D T ^  +  ( V > V C )  ( 3 5 -  2 )
                           The special  operator D/Dt  = d/'dt  + v • V is called  the substantial derivative (meaning that
                           the time rate of change is reported as one moves  with  the "substance"). The terms mater-
                           ial derivative, hydrodynamic derivative, and derivative following the motion are also  used.
                               Now we need  to know  how  to convert  equations  expressed  in terms  of dldt  into
                           equations written with  D/Dt.  For any  scalar  function f(x,  y, z, t) we  can do the  following
                           manipulations:







                                                                                                (3.5-3)
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