Page 49 - Tribology in Machine Design
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36   Tribology in machine design


                                 generalized melting point based on the liquid/vapour critical point will be
                                used


                                 where T c is the critical temperature. Taking into account the expressions
                                 discussed above, the final formula for the fractional film defect, /?, has the
                                 form




                                 Equation (2.67) is only valid for a simple lubricant without any additives.

                                 (ii) Compounded lubricant
                                 To remove the limitation imposed by eqn (2.67) and extending the concept
                                 of the fractional film defect on compounded lubricants, it is necessary to
                                 introduce the idea of temporary residence for both additive and base fluid
                                 molecules on the lubricated metal surface in a dynamic equilibrium. For a
                                 lubricant containing two components, additive (a) and base fluid (b), the
                                 area A m arises from the spots originally occupied by both (a) and (b). Thus,


                                 The fractional film defect for both (a) and (b) can be defined as





                                 where A a and A b represent the original areas covered by (a) and (b),
                                 respectively. The fraction of surface covered originally by the additive,
                                 before contact, is



                                 where A T = A a + A b is the real area of contact.
                                   According to eqn (2.60), the fractional film defect of the compounded
                                 lubricant can be expressed as



                                 From eqn (2.69)


                                 From eqn (2.70)



                                Taking the above into account, eqn (2.68) becomes


                                 Reorganized, eqn (2.71) becomes
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