Page 13 - Vogel's TEXTBOOK OF QUANTITATIVE CHEMICAL ANALYSIS

CONTENTS

10.140 The silver reductor 414
10.141 Other methods of reduction 415

CHAPTER 11 GRAVIME TRY

11.1 Introduction to gravimetric analysis 417
11.2 Precipitation methods 418
11.3 The colloidal state 418
11.4 Supersaturation and precipitate formation 421
11.5 The purity of the precipitate: Co-precipitation 422
11.6 Conditions of precipitation 424
11.7 Precipitation from homogeneous solution 424
11.8 Washing the precipitate 426
11.9 Ignition of the precipitate: Thermogravimetric method of analysis 428
QUANTITATIVE SEPARATIONS BASED UPON PREClPlTATlON METHODS 433
11.10 Fractional precipitation 433
11.1 1 Organic precipitants 437
11.12 Volatilisation or evolution methods 444
PRACTICAL GRAVIMETRIC ANALYSE 446
11.13 Introduction 446
CATIONS 446
11.14 Determination of aluminium as the 8-hydroxyquinolate,
Al(C,H,ON),, with precipitation from homogeneous solution 446
11.15 Ammonium 447
11.16 Antimony 447
11.17 Arsenic 448
11.18 Barium 448
11.19 Beryllium 449
11.20 Bismuth 450
11.21 Cadmium 451
11.22 Calcium 451
11.23 Cerium 453
11.24 Chromium 454
11.25 Cobalt 454
11.26 Copper 455
11.27 Gold 456
11.28 Iron 457
11.29 Lead 458
11.30 Lithium 459
11.31 Magnesium 459
11.32 Manganese 460
11.33 Mercury 461
11.34 Molybdenum 461
11.35 Nickel 462
11.36 Palladium 463
11.37 Platinum 464
11.38 Potassium 464