Page 304 - Materials Chemistry, Second Edition
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                       Incineration of MSW                                                         275
                           • Uncertainty over regulatory requirements
                           • Major long-term economic risks
                           • Initially high capital cost tag and frequent cost overruns
                           • Concern over the effect that a long-term commitment to incineration may have on recy-
                             cling and other conservation efforts


                       9.8  REFUSE-DERIVED FUEL

                       During mass burning of MSW, no processing or separation of the fuel occurs other than simple mix-
                       ing by the tipping vehicle. In contrast, the refuse-derived fuel (RDF) technology employs a two-
                       stage production–incineration system. Wastes are processed to produce a higher quality and more
                       homogeneous fuel product than raw MSW. The input waste is usually shredded to reduce particle
                       size. Ferrous metals are recovered using magnetic separators. Glass, stones, and soil may be
                       removed by trommel screening. In some RDF plants, additional equipment is employed to process
                       the fuel product further, eliminating additional noncombustible materials. The final stages of pro-
                       cessing may involve air classification to remove the lightest fractions of the charge followed by, in
                       some cases, densification to produce a fuel in pellet or briquette form. Ideally, the separated, mostly
                       organic fraction is composed of paper products and nonhalogenated plastics only; however, PVC,
                       food, and yard wastes also occur. The RDF is either marketed to outside customers or burned on-
                       site in a so-called “dedicated” furnace.
                          The practice of selling a solid fuel derived from the physical processing of MSW dates only to
                       the early 1970s. Since that time a number of processes have been developed for RDF production
                       and utilization. Several plants are in operation both in the United States and Europe. RDF facilities
                       represent the smallest portion of the various waste-to-energy facilities studied in a DOE (2001)
                       report. The RDF-only facility came on line in 1975 and gradually increased in number through
                       1991. Reaching the peak in 1990/1991 (29 plants), their numbers have since declined. Of the 38
                       facilities operating since 1975, 15 were still operating in 1998. In addition to combusting RDF only,
                       however, many more plants burn RDF as a co-fuel, i.e., in a mixture with other solid fuels such as
                       coal. Co-firing with coal in a ratio of approximately 75:25 coal/RDF is a fairly typical ratio.
                          The overall benefits of RDF utilization include diverting potentially useful organic materials out
                       of the landfill, energy recovery from solid wastes, and reduction in a number of gaseous pollutants
                       compared with the combustion of coal alone.


                       9.8.1 OVERVIEW OF RDF PREPARATION
                       Although other methods have been tested, the so-called “dry separation” of RDF from municipal
                       wastes is by far the most common method of initial preparation. The method may be adapted to pro-
                       duce various qualities of RDF, depending mostly on the extent of separation of inorganic materials
                       and the putrescible (i.e., rapidly decomposable and potentially malodorous) components from the
                       paper and the plastics in the organic fraction. Because waste may undergo processing for other rea-
                       sons, such as separation of potentially recyclable metals and other inorganics, dry separation is a
                       logical fit for fuel production.
                          In order to separate the organic fraction from metals, glass, and other dense components, it is first
                       necessary to pass the waste through a trommel screen. The incorporation of a screen early in the
                       waste flow can be used either to avoid the need for air classification of the process stream or to
                       remove stones, dirt, and putrescible materials before air classification, so that the RDF contains
                       mostly paper and plastics. Screening may be followed by pulverization in a hammermill or other
                       shredding device. Separation of ferrous metals by magnetic extraction is a next logical step (see
                       Chapter 7). Most systems for RDF production include an air classifier to separate the heavy inorganic
                       components from the largely organic RDF. In some cases, bundled newspaper and cardboard are
                       manually removed from the incoming waste. Most RDF systems in the United States incorporate all
                       organics into the fuel, while many developed in Europe separate mainly paper and plastics.
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