Page 279 - Characterization and Properties of Petroleum Fractions - M.R. Riazi

QC: —/—
P1: KVU/KXT
20:46
June 22, 2007
AT029-Manual-v7.cls
AT029-Manual
AT029-06
TABLE 6.10—Freezing point, heat of fusion, molar volume, and solubility parameters for some selected compounds [DIPPR].
3
T M ,K
3 1/2
Formula
M
V 25 ,cm /mol
δ 25 , (J/cm )
No. P2: KVU/KXT Compound T1: IML 6. THERMODYNAMIC RELATIONS FOR PROPERTY ESTIMATIONS 259
N C
H f /RT M at T M
n-Paraffins
1 Methane CH 4 1 16.04 90.69 1.2484 37.969(52) a 11.6
2 Ethane C 2 H 6 2 30.07 90.35 3.8059 55.229(68) a 12.4
3 Propane C 3 H 8 3 44.09 85.47 4.9589 75.700(84) a 13.1
4 n-Butane C 4 H 10 4 58.12 134.86 4.1568 96.48(99.5) a 13.7
5 n-Pentane C 5 H 12 5 72.15 143.42 7.0455 116.05 14.4
6 n-Hexane C 6 H 14 6 86.17 177.83 8.8464 131.362 14.9
7 n-Heptane C 7 H 16 7 100.20 182.57 9.2557 147.024 15.2
8 n-Octane C 8 H 18 8 114.22 216.38 11.5280 163.374 15.4
9 n-Nonane C 9 H 20 9 128.25 219.66 8.4704 179.559 15.6
10 n-Decane C 10 H 22 10 142.28 243.51 14.1801 195.827 15.7
11 n-Undecane C 11 H 24 11 156.30 247.57 10.7752 212.243 15.9
12 n-Dodecane C 12 H 26 12 170.33 263.57 16.8109 228.605 16.0
13 n-Tridecane C13H 28 13 184.35 267.76 12.8015 244.631 16.0
14 n-Tetradecane C 14 H 30 14 198.38 279.01 19.4282 261.271 16.1
15 n-Pentadecane C 15 H 32 15 212.41 283.07 14.6966 277.783 16.1
16 n-Hexadecane C 16 H 34 16 226.43 291.31 22.0298 294.213 16.2
17 n-Heptadecane C 17 H 36 17 240.46 295.13 16.3674 310.939 16.2
18 n-Octadecane C 18 H 38 18 254.48 301.31 24.6307 328.233 16.2
19 n-Nonadecane C 19 H 40 19 268.51 305.04 18.0620 345.621 16.2
20 n-Eicosane C 20 H 42 20 282.54 309.58 27.1445 363.69 16.2
21 n-Heneicosane C 21 H 44 21 296.56 313.35 18.3077 381.214 16.2
22 n-Docosane C 22 H 46 22 310.59 317.15 18.5643 399.078 16.2
23 n-Triacosane C 23 H 48 23 324.61 320.65 20.2449 416.872 16.3
24 n-Tetracosane C 24 H 50 24 338.64 323.75 20.3929 434.942 16.3
25 n-Hexacosane C 26 H 54 26 366.69 329.25 22.1731 469.975 16.3
26 n-Heptacosane C 27 H 56 27 380.72 332.15 21.8770 488.150 16.2
27 n-Octacosane C 28 H 58 28 394.74 334.35 23.2532 506.321 16.2
28 n-Nonacosane C 29 H 60 29 408.77 336.85 23.6034 523.824 16.2
29 n-Triacontane C 30 H 62 30 422.80 338.65 24.4439 540.500 16.2
30 n-Docontane C 32 H 66 32 450.85 342.35 26.8989 576.606 16.2
31 n-Hexacontane C 36 H 74 36 506.95 349.05 30.6066 648.426 16.2
Isoparaffins
32 Isobutane C 4 H 10 4 58.12 113.54 4.8092 105.238 12.57
33 Isopentane C 5 H 12 5 72.15 113.25 5.4702 117.098 13.86
34 Isooctane (2,2,4-trimethylpentane) C 8 H 18 8 114.23 165.78 6.6720 165.452 14.08
n-Alkylcyclopentanes (naphthenes)
35 Cyclopentane C 5 H 10 5 70.14 179.31 0.4084 94.6075 16.55
36 Methylcyclopentane C 6 H 12 6 84.16 146.58 4.7482 128.1920 16.06
37 Ethylcyclopentane C 7 H 14 7 98.19 134.71 6.1339 128.7490 16.25
38 n-Propylcyclopentane C 8 H 16 8 112.22 155.81 7.7431 145.1930 16.36
39 n-Butylcyclopentane C 9 H 18 9 126.24 165.18 8.2355 161.5720 16.39
n-Alkylcyclohexanes (naphthenes)
40 Cyclohexane C 6 H 12 6 84.16 279.69 1.1782 108.860 16.76
41 Methylcyclohexane C 7 H 14 7 98.18 146.58 5.5393 128.192 16.06
42 Ethylcyclohexane C 8 H 16 8 112.21 161.839 6.1935 143.036 16.34
43 n-Propylcyclohexane C 9 H 18 9 126.23 178.25 6.9970 159.758 16.35
44 n-Butylcyclohexane C 10 H 20 10 140.26 198.42 8.5830 176.266 16.40
45 n-Decylcyclohexane C 16 H 32 16 224.42 271.42 17.1044 275.287 16.65
n-Alkylbenzenes (aromatics)
46 --`,```,`,``````,`,````,```,,-`-`,,`,,`,`,,`--- Benzene C 6 H 6 6 78.11 278.65 4.2585 89.480 18.70
47 Methylbenzene (Toluene) C 7 H 8 7 92.14 178.15 4.4803 106.650 18.25
48 Ethylbenzene C 8 H 10 8 106.17 178.15 6.1983 122.937 17.98
49 Propylbenzene C 9 H 12 9 120.20 173.55 6.4235 139.969 17.67
50 n-Butylbenzene C 10 H 14 10 134.22 185.25 7.2849 156.609 17.51
51 n-Pentylbenzene C 11 H 16 11 148.25 198.15 9.2510 173.453 17.47
52 n-Hexylbenzene C 12 H 18 12 162.28 211.95 10.4421 189.894 17.43
53 n-Heptylbenzene C 13 H 20 13 176.30 225.15 11.6458 206.428 17.37
54 n-Octylbenzene C 14 H 22 14 190.33 237.15 13.1869 223.183 17.37
55 n-Nonylbenzene C 15 H 24 15 204.36 248.95 13.9487 239.795 17.39
56 n-Decylbenzene C 16 H 26 16 218.38 258.77 15.1527 256.413 17.28
57 n-Undecylbenzene C 17 H 28 17 232.41 268.00 16.1570 272.961 17.21
58 n-Dodecylbenzene C 18 H 30 18 246.44 275.93 17.5238 289.173 17.03
59 n-Tridecylbenzene C 19 H 32 19 260.47 283.15 18.6487 306.009 16.87
60 n-Tetradecylbenzene C 20 H 34 20 274.49 289.15 19.8420 322.197 16.64
61 n-Pentadecylbenzene C 21 H 36 21 288.52 295.15 20.9874 339.135 16.49
(Continued )

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