Page 160 - Materials Chemistry, Second Edition
P. 160

9 Life Cycle Inventory Analysis                                 145

            specificity. A large part of the data collection therefore usually takes place online by
            searching, identifying and accessing publicly available sources, such as other LCA
            studies, industry association reports and national statistics. It is also possible to
            identify, via online searching, data for a process that is very similar to the actual
            process to be modelled, either because the reference flow of the processes is the
            same (e.g. the incineration of polypropylene) or similar (e.g. the incineration of
            polypropylene versus polyethylene). The strategy of extrapolation from data for
            similar processes is especially useful to ‘fill out gaps’ in a preliminary unit process,
            but the LCA practitioner must carefully check the representativeness of the process
            used for extrapolation. For example, if the initial data collection effort has led to a
            handful of high or very high specificity emission data, but no resource inputs for a
            process, the remaining flows may be quantified by extrapolation from a similar
            process. Such similar process can be sourced from scientific papers or other
            sources, which can document sufficient representativeness (technology, geography,
            time) and disclose sufficient data to check the agreement with the existing handful
            of high specificity emission data for the original unit process. A special case of
            extrapolation is for novel technologies that may not yet operate at industrial scale
            anywhere at the point in time where the study is to be conducted. Here, an obvious
            source of extrapolation is laboratory scale processes. It is, however, important to
            consider how the relationships between the flows of a process changes from lab-
            oratory to industrial scale. Often the technology of the process will change, not just
            in size, at the upscaling from lab scale to commercial scale, and this typically leads
            to increased efficiency (e.g. less input per reference flow output) and changes in the
            quality of flows.
              The effort required to access data via online searching depends on the expertise
            of the practitioner (e.g. familiarity with the terminology of the concerned technical
            domain) and on how well-studied the phenomena behind the data is. For example,
            there is generally more publically available data on greenhouse gas emissions than
            on emissions of synthetic chemicals used for very specific industrial purposes and
            produced in low volumes. The effort also depends on the number of data points that
            can be accessed from each source. A unit process is often composed of more than
            100 flows (the majority often being elementary flows). Some sources, such as LCI
            databases, contain data for all flows making up a unit process, while other sources,
            e.g. statistical agencies, may only cover a few elementary flows.
              LCI databases are used to source data for the background system and for the
            parts of the foreground system where more specific data can or will not be obtained.
            Table 9.5 presents a non-exhaustive list of LCI databases.
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