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Guo, Boyun / Computer Assited Petroleum Production Engg 0750682701_chap16 Final Proof page 247 21.12.2006 2:30pm




                                                                                     MATRIX ACIDIZING  16/247
                       Example Problem 16.2 A 60-ft thick, 50-md sandstone
                       pay zone at a depth of 9,500 ft is to be acidized with an
                       acid solution having a specific gravity of 1.07 and a
                       viscosity of 1.5 cp down a 2-in. inside diameter (ID) coil
                       tubing. The formation fracture gradient is 0.7 psi/ft. The
                       wellbore radius is 0.328 ft. Assuming a reservoir pressure
                       of 4,000 psia, drainage area radius of 1,000 ft, and a skin
                       factor of 15, calculate
                       (a) the maximum acid injection rate using safety margin
                          300 psi.
                       (b) the maximum expected surface injection pressure at
                          the maximum injection rate.
                       Solution
                       (a) The maximum acid injection rate:

                              4:917   10  6  kh p bd   p   Dp sf
                        q i, max ¼
                                   m a ln  0:472r e  þ S
                                        r w
                                      6
                              4:917   10 (50)(60) (0:7)(9,500)   4,000   300Þ
                                            ð
                            ¼
                                      (1:5) ln  0:472(1,000) þ 15
                                             (0:328)             Figure 16.2 Wormholes created by acid dissolution of
                            ¼ 1:04 bbl=min                       limestone (Hoefner and Fogler, 1988; courtesy AIChE).
                       (b) The maximum expected surface injection pressure:
                                                                 16.4.2 Acidizing Parameters
                          p wf ¼ p bd   Dp sf ¼ (0:7)(9,500)   300 ¼ 6,350 psia
                                                                 Acidizing parameters include acid volume, injection rate,
                          Dp h ¼ (0:433)(1:07)(9,500) ¼ 4,401 psi  and injection pressure. The acid volume can be calculated
                              518r 0:79 1:79 m 0:207             with two methods: (1) Daccord’s wormhole propagation
                                    q
                          Dp f ¼          L                      model and (2) the volumetric model, on the basis of desired
                                 1,000D 4:79                     penetration of wormholes. The former is optimistic, whereas
                              518(1:07) 0:79 (1:04) 1:79 (1:5) 0:207  the latter is more realistic (Economides et al., 1994).
                             ¼                     (9,500)
                                     1,000(2) 4:79                 Based on the wormhole propagation model presented by
                             ¼ 218 psi                           Daccord et al. (1989), the required acid volume per unit
                                                                 thickness of formation can be estimated using the follow-
                           p si ¼ p wf   Dp h þ Dp f             ing equation:
                             ¼ 6,350   4,401 þ 218 ¼ 2,167 psia
                                                                             r
                                                                     pfD 2=3 1=3 d f
                                                                          q
                                                                 V h ¼     h  wh                     (16:9)
                                                                        bN Ac
                                                                 where
                       16.4 Carbonate Acidizing Design
                       The purpose of carbonate acidizing is not to remove  V h ¼ required acid volume per unit thickness
                                                                                   3
                       the damage to the formation near the wellbore, but to  of formation, m =m
                       create wormholes through which oil or gas will flow after  f ¼ porosity, fraction
                                                                                               2
                       stimulation. Figure 16.2 shows wormholes created by acid  D ¼ molecular diffusion coefficient, m =s
                       dissolution of limestone in a laboratory (Hoefner and  q h ¼ injection rate per unit thickness of
                                                                                 3
                       Fogler, 1988).                                   formation, m =sec-m
                         Carbonate acidizing is a more difficult process to pre-  r wh ¼ desired radius of wormhole penetration, m
                       dict than sandstone acidizing because the physics is much  d f ¼ 1:6, fractal dimension
                       more complex. Because the surface reaction rates are very  b ¼ 105   10  5  in SI units
                       high and mass transfer often plays the role of limiting  N Ac ¼ acid capillary number, dimensionless,
                       step locally, highly nonuniform dissolution patterns are
                       usually created. The structure of the wormholes depends  where the acid capillary number is defined as
                       on many factors including flow geometry, injection rate,  fbg a
                       reaction kinetics, and mass transfer rates. Acidizing de-  N Ac ¼  (1   f)g m  ,  (16:10)
                       sign relies on mathematical models calibrated by labora-
                       tory data.
                                                                   Table 16.3 Recommended Acid Type and
                       16.4.1 Selection of Acid                              Strength for Carbonate Acidizing
                       HCl is the most widely used acid for carbonate matrix
                       acidizing. Weak acids are suggested for perforating fluid  Perforating fluid:  5% acetic acid
                       and perforation cleanup, and strong acids are recom-  Damaged perforations:  9% formic acid
                       mended for other treatments. Table 16.3 lists recom-                 10% acetic acid
                       mended acid type and strength for carbonate acidizing                15% HCl
                       (McLeod, 1984).                             Deep wellbore damage:    15% HCl
                         All theoretical models of wormhole propagation predict             28% HCl
                       deeper penetration for higher acid strengths, so a high              Emulsified HCl
                       concentration of acid is always preferable.
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