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158                  30 Fibre Reinforced Polymer Composites

                 7.3 INTERLAMINAR FRACTURE TOUGHNESS

                 It  has been previously  mentioned that the open nature of  the  knit architecture gives
                  these fabrics the ability to nest very closely between individual fabric layers. Some knit
                  architectures also consist of  2  or  more fabric layers that  are integrally connected by
                  knitting yarns. Both these  attributes of  knitted fabrics will promote the formation of
                  fibre  bridging  mechanisms  that  should  enhance  the  fracture  toughness  of  knitted
                  composites.
                    Mode I fracture tests have been  performed upon  a range of  E-glasdepoxy  warp
                  knitted  composite  materials  (Huysmans  et  a].,  1996), E-glasdepoxy  weft  knitted
                  composites (Kim et al., 2000) and E-glasdvinyl ester weft knitted composites (Mouritz
                  et al.,  1999).  In all cases the fracture toughness measurements of  knitted composites
                  were significantly higher than those of typical 2D woven, unidirectional or random mat
                  composites.  Huysmans et a1  (1996) measured Mode I fracture toughness levels of 5.5
                  to  6.5  kJ/m2  for  specimens  of  warp  knitted  E-glasdepoxy  containing  a  tissue
                  architecture. This is  in  direct comparison to typical values of  1.2 and 0.6 kJ/m2 for
                  woven and unidirectional E-gladepoxy materials respectively.  Mouritz et al. (1999)
                  conducted an extensive comparison of  the fracture toughness of  milano weft knitted
                  composites against a range of  unidirectional, 2D  woven, 2D  braided, 3D  woven and
                  stitched  E-glass/vinyl  ester  materials.   The  authors  found  that  their  toughness
                  measurements  for  the  knitted  composites  of  up  to  3.3  H/m2  were  not  only
                  approximately four times that of 2D woven materials but were also significantly higher
                  than  those  measured  for  the  2D  braided, stitched  and  3D  woven  materials.  Both
                  Huysmans et al.  (1996) and Mouritz et al. (1999) examined the  fracture path of  the
                  knitted composite and found that the highly looped nature of the yarn architecture had
                  forced the crack to follow a very tortuous path with extensive crack branching.  They
                  concluded that  this combination of  crack path deflection  and  crack branching is the
                  likely cause of the high interlaminar fracture toughness.
                    Mouritz et al. (1999) also noted that the fracture toughness of the knit decreased
                  when the stitch density of the knitted fabric increased.  This was also observed by Kim
                  et al. (2000) who measured the Mode I fracture toughness of milano weft knitted E-
                  glasslepoxy  composites  at  a  range  of  tightness  factors,  this  factor  being  directly
                  proportional to the stitch density (see Table 7.6). They found that as the tightness factor
                  increased the measured fracture toughness decreased in an approximately linear fashion.
                  This effect is due to the fact that as the tightness factor (or stitch density) increases the
                  knit architecture becomes progressively less open. When the fabric layers are placed
                  together the fabric with a  higher stitch density will  nest, or intermingle, less than  a
                  fabric with an open structure.  This lower degree of intermingling will result in a less
                  tortuous crack path and thus a lower value of fracture toughness.


                  Table 7.6 Mode I fracture toughness of E-glass/epoxy weft knitted milano composites
                  (from Kim et al., 2000)
                        Material   Fibre volume fraction (%)  Tightness factor  GI, (kJ/mZ)
                        Milano 1            20.1               1.30         4.05
                        Milano 2            22.3               1.44         3.22
                        Milano 3            24.8               1.61         2.58
                        Milano 4            27.4               1.73         2.29
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