Page 108 - A Practical Introduction to Optical Mineralogy
P. 108

SILICATE  MINERALS                                                           OLIVINE GROUP
                                                                                                          80
                  coLOUR  Usually colourless, but may appear pale yellow if Fe + content very high.       +  ~
                                                            2
               PLEOCHROISM  Extremely rare; only Fa olivines may show a  and {3  pale yellow, withy       90  --- ~          -- -- --- 1--- --- --
                                                                                                                    -- - -
                        yellow.
                                                                                                       ~            ~
                    HABIT  In igneous rocks olivine ranges from anhedral (plutonic rocks) to sub-       V>  (!)         r-....
                                                                                                        (!)   80          .......
                                                                                                        ....
                        hedral (extrusive rocks). A  rough six-sided crystal shape can be seen in       on
                                                                                                                                <Vo:
                                                                                                        (!)                 ~
                        basalts where the olivine occurs as  phenocrysts.                              :s   70
                                                                                                        (!)
                 cLEAVAGE  {010}  poor with  rare {100}  imperfect fracture.                           o;,                        ..........
                   RELIEF  Variable depending upon composition;  forsterite  is  moderate  to  high     c:   60                     !'..........
                                                                                                        "'
                                                                                                       ;:,.                              ...........
                        and fayalite  very  high.
                                                                                                       N                                    ~'-.......
               • ALTERATION  Olivine  is  very  susceptible  to  hydrothermal  alteration,  low  grade
                                                                                                          50
                        metamorphism and the effects of weathering. Mixtures of products are                                                     ...........
                        produced, the most common being serpentine, chlorite, talc, carbonates,           40
                        various iron oxides and iddingsite and bowlingite (which appear to be
                        mixtures of hydrated iron oxides including goethite and hematite). The            1.90
                        most common reaction is  that of olivine altering to serpentine:
                                                                                                          1.85                                ---~
                                   3  olivine + water + silica ~ serpentine                                                                 ~
                                                                                                        c:                          ny  ~  ~
                                                                                                        .2                                  ,....,.....
                                                                                                        ti   1.80                   v
                        serpentine may  break down further to  talc and carbonates.                     ~                       ~       v--
                                                                                                                        v
                          Some  alteration  of olivine  is  usually  present  along  irregular  basal   e  1.75             L..---::::   ~
                                                                                                                            .......
                        fractures and poor cleavages, and complete alteration can occur with the        0           ~  v        v   n"
                                                                                                        X
                        olivine crystal totally replaced by serpentine, often with a release of iron    (!)   1.70   ./   ./
                                                                                                        '0          v
                        ores.                                                                           c:   t:::::: B
             *BIREFRINGENCE  High, with maximum interference colour lower third order (for iron-rich      1.65  v
                        olivines).
              *INTERFERENCE  2V is generally very large, and a single isogyre should be examined from      60
                   FIGURE   an isotropic section. Such a grain will  not appear black on rotation but     1.  100   90   80   70   60   50   40   30   20   10   ()
                                                                                                            Fo                                    Fa
                        will  appear greyish, owing to the high  relief and dispersion of olivine.
                        The  optic axis  figure  will  show  an  isogyre  in  which  the  direction  of
                                                                                                     Figure 2.19  Variation of 2V angle and indices of refraction for the forsterite-
                        curvature is  difficult to determine if 2V is  very large (>  80°). Olivines
                                                                                                     fayalite  (olivine) series (after Bowen &  Schairer 1935).
                        from most basic igneous rocks have a compositional range of Fo 85 Fa 15  to
                        Fo, 0 Fa 50 ,  which  represents a  2V range  of from  90°  to 75° (Fig.  2.19).
                EXTINCTION  Straight on  poor {010} cleavage or prism  face.                          Olivines may show reaction rims against plagioclase crystals (called
                 TWINNING  Rare in  most olivines. Sometimes broad deformation lamellae parallel     kelyphitic  margins  or  corona  structures)  in  metamorphosed  basic
                        to (100)  occur in  ultramafic igneous rocks.                                igneous  rocks  or  in  some  ultrabasic  troctolites,  where  an  olivine  or
             OTHER FEATURES  Zoning is  occasionally present but is  not a diagnostic feature.  Mg-rich   olivine plus serpentine kernel is surrounded by successive rims of pyrox-
                        olivine  may  contain  minor  amounts  of  trivalent  ions  which  may  be   ene and garnet or spinel and amphibole. In basic igneous rocks contain-
                        exsolved as tiny  inclusions of chromite or magnetite.                       ing  Mg-rich olivine, quartz is  never present since it  would have com-
               OCCURRENCE  Mg-rich olivine is an essential mineral in most ultra basic igneous rocks -  bined  with  the  olivine  in  the  crystallising  magma  to  give  more
                        dunites, peridotites and picrites. Olivine is  also common in  many basic    orthopyroxene;  however,  in  some later stage  iron-rich  igneous  rocks
                        igneous rocks such as gabbros, dolerites and basalts, and more Fe-rich       (syenogabbros, ferrogabbros) , iron-rich  olivine coexists with quartz.
                        olivine  may occur in  some undersaturated igneous rocks such as larvi-
                        kites,  teschenites  and  alkali  basalts.  Iron-rich  olivine  occurs  in  some
                        ferrogabbros,  trachytes  and  syenites.  Olivine  can  occur  in  meta-
                        morphosed  basic  igneous  rocks  and  metamorphosed  dolomitic  lime-
                        stones,  in  which  the olivine  is  nearly  pure forsterite .
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