Page 156 - A Practical Introduction to Optical Mineralogy
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THE  NON-SILICATES                                                        SULPHIDES
                                                                                                  Covellite  is  hexagonal,  a: c  =  1: 1.43026.  It  occurs  as  platy  { 0001}
                Cinnabar  HgS                                                               Crystals
                  Crystals  Cinnabar  is  trigonal,  a: c  =  1: 2.2905,  and  occurs  as  thick  tabular   crystals with  a perfect { 0001}  basal cleavage. D  =  4.6.
                        { 0001} or P!ismatic [ 10il] crystals. There is a { 0001} twin plane and   Thin section  Covellite is  greenish in  very thin  flakes.
                                                                                                  Covellite is blue and strongly pleochroic from blue to bluish light grey,
                        perfect { 1011}  cleavage.  D  = 8.09.                              Polished
               Thin section  Cinnabar  is  deep  red.  Refractive  index  values  (A.  = 598  nm)  are   section   except  in  basal  sections  which  remain  blue.  Ro  = 7  and  R.  = 22%.
                                                                                                  Anisotropy is  very strong with  bright ' fiery'  orange colours.
                        n 0  =  2.905  and n.  =  3.256.
                                                                                                  Covellite occurs as idiomorphic platy crystals and flakes as well as rather
                 Polished  Cinnabar  is  light  grey  to  bluish  light  grey,  weakly  pleochroic,  with
                                                                                                  'micaceous' aggregates. The good basal cleavage, parallel to the length
                  section  Ro = 28% and R.  = 29%. Anisotropy is  moderate with greenish grey
                                                                                                  of grains, is  often  deformed.  VHN = 69-78.
                        tints,  but  these  are  often  masked  by  abundant  deep  red  internal
                                                                                                                                  Covellite
                        reflections.
                        Cinnabar  occurs  as  granular  aggregates  and  idiomorphic  crystals.                                   basal section (B) and cross
                                                                                                                                  sections of covellite showing
                        Deformation multiple twinning may be present. As a result of variation                                    cleavage traces (C): chalcoctte
                        in  polishing  hardness  with  orientation,  granular  aggregates  may  re-                               (Ch) is  replacing the covellite
                        semble a  two  phase intergrowth  at first  glance.
                Occurrence  Cinnabar  is  rare,  occurring  in  low  temperature  hydrothermal  veins,
                        impregnations and  replacement deposits  often associated  with  recent
                        volcanics. It often replaces quartz and sulphides and is  associated with
                        native mercury, mercurian tetrahedrite-tennantite, stibnite, pyrite and
                        marcasite in  siliceous gangue.  VHN  =  51-98.
              Distinguishing  Compared with cinnabar, hematite is brighter, harder and has very rare
                  features  internal  reflections;  pyrargyrite  is  very  similar  but  with  less  intense
                                                                                                                                      500 IJ.m   I PPL
                        internal reflections; and cuprite Cu 2 0  is bluish grey, harder and usually
                        associated with  native copper.
                   Notes  Metacinnabarite  is  a  high  temperature  cubic  polymorph  of  HgS.  It
                                                                                                   Covellite commonly occurs as a 'secondary' mineral after Cu + Fe  + S
                        occurs as grains within cinnabar and is  slightly darker, isotropic, lacks   Occurrence
                        internal  reflections and is  softer than cinnabar.                        minerals, often  in  the zone of secondary enrichment.
                                                                                         Distinguishing   Covellite is easy to identify. Digenite is blue but neither pleochroic nor
                Cobaltite  CoAsS                                                             features  anisotropic.
                        Cobaltite may contain significant amounts of Fe and Ni in solid solution.   Notes   Blaubleibender covellite Cu,+xS occurs with covellite and is identical in
                  Crystals  Cobaltite is orthorhombic (pseudo-cubic). It commonly occurs in cubes   appearance except  under oil immersion, when:   R.  =  bluish  grey
                        or  pyritohedrons  but  may  be  octahedral.  There  is  a  perfect  { 001}   covellite        R 0  =  reddish  purple   R. = bluish grey
                        cleavage. D  = 6.0-6.3.                                                    blaubleibender covellite   R 0  = deep  blue
                 Polished  Cobaltite  is  pinkish  white  with  R  = 53 %,  similar  to  pyrite.  Both
                  section  bireflectance and anisotropy,  with  brownish  to  bluish  tints,  are weak.   Galena  PbS
                                                                                                    Galena  may  possibly  contain  some  Se,  Te,  Ag,  Sb,  Bi,  As  in  solid
                        Cobaltite  is  often  idiomorphic and  of 'cubic'  morphology.  It  may  be
                                                                                                    solution but usually only in  trace amounts.
                        granular or skeletal. Colour zonation has been observed and complex         The crystallographic symmetry of galena is cubic and crystals are com-
                        fine  lamellar  twinning  and  cleavage  traces  may  be  present.    Crystals
                                                                                                    monly  cubic,  cuba-octahedral  and  (less  often)  octahedral  in  shape
                        VHN  =  1176-1226.
                                                                                                    (Fig. 3.5).  Twinning on  { 111}  is  common  and lamellar twinning  may
                Occurrence  It is associated with Cu + Fe + Sand Co + Ni  + As minerals in high to
                        medium  temperature deposits in  veins  and as disseminations.              occur on {114}.  There is  a  perfect {001}  cleavage.  D  =  7.58.
              Distinguishing  Compared with  cobaltite, pyrite  is  yellowish  and harder.
                  features
                Covellite  CuS                                                          Figure3.5
                        Covelline  is  an  alternative  name  recommended  by  the  International   Typical galena
                        Mineralogical  Association.                                     crystals.
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