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                    124                             3. Heterogeneous Processes and Reactor  Analysis







                                   35
                                   30  separated      chain     transition  jet
                                       bubbles       bubbling             regime
                                   25
                                   20

                                  (mm)  15
                                  b
                                 d
                                   10
                                    5               higher orifice
                                                      diameter
                                    0
                                   0.0001  0.001  0.01    0.1      1
                                           gas flow rate at orifice opening*orifice diameter
                        Figure 3.33  Air-bubble formations at the orifice in water (Heijnen and an’t Riet, 1984). V

                      Addition of solids in the liquid increases the bubble coalescences, and in turn, the b ub-
                    ble size (K 1996). Fukuyama et al. (1987) proposed the following correlation for
                     oide,
                    slurry bubble columns:
                                                      0.59        2
                                                 d                                    (3.188)
                                                  bub        
                                                        g  h  G  


                                                               1    h  
                                                   h
                                             u   (1    )    u h    G                  (3.189)
                                               sG   G   sL G     h  L   
                    Bubble diameter dbub is also referred to as “volume-surface mean diameter of bubbles” or
                    “Sauter mean bubble diameter.” SI units are used with this correlation.
                      The Rayleigh–Taylor instability is the balance of surface tension and gravity acting on
                     ,
                    a gas bubble. If the latter is greater than the former the bubble will eentually break up. v
                    According to Bellman and Pennington (1953), if the diameter of a certain spherical cap
                    ,
                    bubble exceeds a critical diameter it will break up. This critical diameter is referred to as
                    the maximum stable bubble size and is generally expressed as (Bellman and Pennington,
                    1953; Behkish, 2004)

                                                          
      0.5
                                            d       2       L                       (3.190)
                                             x bub,ma   g (
                                                          L  G  )  

                    Krishna   et al.  (2001) used a different and simpler approach for determining the bubble ris-
                    ing velocity and bubble diameter. They employed a two-phase model, analogous to the one
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