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102    CHAPTER 5 RATIONAL EFFICIENCY OF POWER PLANT




             same two temperature limits (T 3s and T 1 ). If T 0 is not equal to T 3 , but is equal to a lower temperature,
             T L , then the rational efficiency will be less than unity because energy which has the capacity to
               0
             do work is being rejected. This is depicted by area C in Fig 5.1(b), and the rational efficiency
             becomes

                                Areas ðA þ B þ CÞ  Areas ðB þ CÞ    Area A
                            h ¼                                ¼             < 1           (5.9)
                             R
                                   Areas ðA þ B þ CÞ  Area ðBÞ   Areas ðA þ CÞ
                Consideration of Eqn (5.8) shows that it is made up of a number of different components which
             can be categorised as available energy and unavailable energy. This is similar to exergy, as shown
             below
                              b ¼ a   a 0 ¼ h   h 0   T 0 ðs   s 0 Þ ¼  E     F           (5.10)
                                          |fflfflffl{zfflfflffl}  |fflfflfflfflfflfflffl{zfflfflfflfflfflfflffl}  |{z}  |{z}
                                          available  unavailable  available  unavailable
                                           energy    energy    energy   energy

                Thus Eqn (5.7) may be rewritten
                               b w net ¼ b 2   b 1 ¼ h 2   h 1   T 0 ðs 2   s 1 Þ¼ dE 12   dF 12 ;  (5.11)

             giving Eqn (5.8) as
                              w net  h 2   h 1   T 3s ðs 2   s 1 Þ  dE 12   dF 12  ðT 3s   T 0 Þðs 2   s 1 Þ
                  h ¼ h 2;th  ¼  ¼                    ¼                                   (5.12)
                   R
                              b w net  h 2   h 1   T 0 ðs 2   s 1 Þ  dE 12   dF 12
             which can be written as
                                                     ðT 3s   TÞðs 2   s 1 Þ
                                       h ¼ h 2;th  ¼ 1               :                    (5.13)
                                        R
                                                        dE 12   dF 12
                If T 0 ¼ T 3s then the rational efficiency, h R ¼ 1.0. If T 0 < T 3s , as would be the case if there were
             external irreversibilities, then h R < 1.0 because the working fluid leaving the engine still contains the
             capacity to do work.
                If the engine is not internally reversible then the T–s diagram becomes 1-2-3-4-1, as depicted in Fig
             5.1(b). The effect of the internal irreversibility is to cause the entropy at 3 to be bigger than that at 3s,
             and hence the entropy difference, dS 34 > dS 12 . The effect of this is that the net work becomes

                           w net ¼ðh 2   h 1 Þ ðh 3   h 4 Þ¼ T 1 ðs 2   s 1 Þ  T 3 ðs 3   s 4 Þ
                               ¼ T 1 ðs 2   s 1 Þ  T 3 ðs 3s   s 4 Þ  T 3 ðs 3   s 3s Þ

                               ¼ h 2   h 1   T 0 ðs 2   s 1 Þ ðT 3   T 0 Þðs 2   s 1 Þ  T 3 ðs 3   s 3s Þ
                               ¼ dE 12   dF 12  ðT 3   T 0 Þðs 2   s 1 Þ  T 3 ðs 3   s 3s Þ  (5.14)
                Hence, from Eqn (5.14)
                                               ðT 3   T 0 Þðs 2   s 1 Þþ T 3 ðs 3   s 3s Þ
                                 h ¼ h 2;th  ¼ 1                           :              (5.15)
                                  R
                                                        dE 12   dF 12
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