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16.4 DIESEL (COMPRESSION IGNITION) ENGINES          357




               first fuel that is injected into the cylinder is not ready to ignite until it has evaporated and produced the
               necessary conditions for hypergolic combustion. This takes a finite time, referred to as the ignition
               delay period, during which the fuel is prepared but not yet ignited. At the end of this period, there is
               rapid combustion of the premixed fuel and air, which gives rise to a high rate of heat release and
               produces high temperatures in the combustion chamber. This period has a major effect on the amount
               of NO x produced in the engine. Typical equations for the ignition delay period are:

                                                  0:446 e ð4650=T igÞ
                                             t ig ¼     1:19    ms                        (16.15a)
                                                       p ig
                  Or one developed by Hardenberg and Hase (1979)

                                                   h               i
                                                                  0:63

                                                       1  1   21:2
                                                    E A  <T     17190  p 12:4
                                t ig ¼ 0:36 þ 0:22V p e                crank angle        (16.15b)
               where
                  V p ¼ mean piston speed (m/s)
                  p ¼ pressure (bar)
                  T ¼ temperature (K)
                  E A ¼ activation energy ¼ 618,840/(CN þ 25)
                  CN ¼ cetane number
                  Both Eqns (16.15a) and (16.15b) have a similar form, and are related to the Arrhenius equation
               introduced in Section 14.3 to define the rate equations. Equation (16.15b) is a more recent formulation
               than Eqn (16.15a), and has a more complex structure. Both equations are the result of experimental
               tests on engines with a range of fuels, and cannot be extended far beyond the regime under which they
               were evaluated, but they do give a basic structure for ignition delay. It should be noted that Eqn
               (16.15b) contains a term for the CN of the fuel. The value of E A reduces as the CN increases and this
               means that the ignition delay is inversely related to CN. A mechanical method for limiting the overall
               ignition delay is to use two-stage or split injection. In this type of system, a small quantity of pilot fuel
               is injected into the cylinder some time prior to the main injection process. The pilot charge is prepared
               and ready to ignite before the main charge enters the chamber, and in this way, the premixed
               combustion is limited to the pilot charge.
                  After the premixed period is over the main combustion period commences, and this is dominated
               by diffusion burning, controlled by the mixing of the fuel and air. Whitehouse and Way (1970)
               attempted to model both periods by the two equations given below.
                  Reaction rate
                                                          Z a

                                                       E A
                                               K p O 2
                                           R ¼   p ffiffiffiffi e  T  ðP   RÞda                   (16.16a)
                                               N  T
                                                          a inj
               and, preparation rate
                                                    0
                                               P ¼ K m ð1 xÞ  x  Þ z                      (16.16b)
                                                           u
                                                      i   m ðp O 2
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